N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed Mizoroki-Heck reaction of aryl chlorides with styrenes

A well-defined N-heterocyclic carbene-palladium(II)-1-methylimidazole [NHC-Pd(II)-Im] complex 1 was found to be an effective catalyst for the Mizoroki-Heck reaction of a variety of aryl chlorides with styrenes. Both activated and deactivated aryl chlorides work well to give the corresponding couplin...

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Bibliographic Details
Published in:Beilstein journal of organic chemistry 2012-11, Vol.8 (1), p.1916-1919
Main Authors: Gao, Ting-Ting, Jin, Ai-Ping, Shao, Li-Xiong
Format: Article
Language:English
Subjects:
aryl chloride
Chemistry
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Mizoroki–Heck reaction
N-heterocyclic carbene
palladium complex
synthetic method
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Summary:A well-defined N-heterocyclic carbene-palladium(II)-1-methylimidazole [NHC-Pd(II)-Im] complex 1 was found to be an effective catalyst for the Mizoroki-Heck reaction of a variety of aryl chlorides with styrenes. Both activated and deactivated aryl chlorides work well to give the corresponding coupling products in good to excellent yields by using tetrabutylammonium bromide (TBAB) as the ionic liquid.
ISSN:1860-5397
1860-5397
DOI:10.3762/bjoc.8.222