N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed Mizoroki-Heck reaction of aryl chlorides with styrenes

A well-defined N-heterocyclic carbene-palladium(II)-1-methylimidazole [NHC-Pd(II)-Im] complex 1 was found to be an effective catalyst for the Mizoroki-Heck reaction of a variety of aryl chlorides with styrenes. Both activated and deactivated aryl chlorides work well to give the corresponding couplin...

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Published in:Beilstein journal of organic chemistry 2012-11, Vol.8 (1), p.1916-1919
Main Authors: Gao, Ting-Ting, Jin, Ai-Ping, Shao, Li-Xiong
Format: Article
Language:English
Subjects:
aryl chloride
Chemistry
Full Research Paper
Mizoroki–Heck reaction
N-heterocyclic carbene
palladium complex
synthetic method
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cited_by cdi_FETCH-LOGICAL-c444t-2ab685720216e91d34a154eef28db89308d964f56d40cecaf0f2b1f7d14872b3
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container_title Beilstein journal of organic chemistry
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creator Gao, Ting-Ting
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Shao, Li-Xiong
description A well-defined N-heterocyclic carbene-palladium(II)-1-methylimidazole [NHC-Pd(II)-Im] complex 1 was found to be an effective catalyst for the Mizoroki-Heck reaction of a variety of aryl chlorides with styrenes. Both activated and deactivated aryl chlorides work well to give the corresponding coupling products in good to excellent yields by using tetrabutylammonium bromide (TBAB) as the ionic liquid.
doi_str_mv 10.3762/bjoc.8.222
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subjects aryl chloride
Chemistry
Full Research Paper
Mizoroki–Heck reaction
N-heterocyclic carbene
palladium complex
synthetic method
title N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed Mizoroki-Heck reaction of aryl chlorides with styrenes
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