Recent Advances in π-Stacking Interaction-Controlled Asymmetric Synthesis

The π-stacking interaction is one of the most important intramolecular and intermolecular noncovalent interactions in organic chemistry. It plays an important role in stabilizing some structures and transition states in certain reactions via both intramolecular and intermolecular interactions, facil...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2024-04, Vol.29 (7), p.1454
Main Author: Xu, Jiaxi
Format: Article
Language:English
Subjects:
Alcohol
Amino acids
asymmetric induction
asymmetric synthesis
Biodegradation
Chemical properties
diastereoselectivity
Organic compounds
Oxidation
Proteins
Synthesis
π-stacking interaction
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Summary:The π-stacking interaction is one of the most important intramolecular and intermolecular noncovalent interactions in organic chemistry. It plays an important role in stabilizing some structures and transition states in certain reactions via both intramolecular and intermolecular interactions, facilitating different selectivities, such as chemo-, regio-, and stereoselectivities. This minireview focuses on the recent examples of the π-stacking interaction-controlled asymmetric synthesis, including auxiliary-induced asymmetric synthesis, kinetic resolution, asymmetric synthesis of helicenes and heterohelicenes, and multilayer 3D chiral molecules.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules29071454