Prospective life cycle assessment of CO2 conversion by photocatalytic reaction

• Published in: Green chemical engineering 2024-09, Vol.5 (3), p.383-389
• Main Authors: Wang, Jun-Qi, Liu, Xiang-Jun, Ma, Jing-Jing, Zhang, Shuai, Liu, Hao-Ran, Dong, Yong-Li, Yang, Qing-Yuan
• Format: Article
• Language: English
• Subjects: CO2; Life cycle assessment (LCA); Photocatalytic reaction; Sensitivity analysis; Uncertainty analysis
• ISSN: 2666-9528; 2666-9528
• DOI: 10.1016/j.gce.2023.10.003

CO2 conversion is gradually seen as a better way for society to effectively use carbon sources and avoid climate crisis associated with fossil CO2 emissions. And the decision to deploy CO2 technology scale should be relied on its environmental impact. In this work, life cycle assessment model evaluates the environmental performance of CO2 conversion by photocatalytic reaction process with two different catalysts (NiAl-LDH and Co-ZIF-9). Six impact categories considered in this analysis, including climate change, acidification potential, depletion of abiotic resources, eutrophication potential, ozone layer depletion potential, and photochemical oxidation potential. Results indicated that CO2 conversion with Co-ZIF-9 photocatalyst has a better environmental impact than the NiAl-LDH photocatalyst route. Moreover, the Co-ZIF-9 catalyst scenario also has a lower total environmental burden than the conventional CO production route. Sensitivity analysis shows that recycle performance of the catalyst is highly sensitive to the production process in two scenarios. This study could provide a framework for robust decisions in CO2 conversion by photocatalytic reaction, which is useful for policymakers to decide the feasibility of industrialization. [Display omitted] •The LCAs of NiAl-LDH and Co-ZIF-9 in photocatalytic reaction were analyzed.•Co-ZIF-9 has a better environmental impact than NiAl-LDH in CO2 photocatalysis.•Sensitivity analysis shows that catalyst recycle has highly sensitive in whole process.