Assessment of the Harmfulness of Moulding Sands with Alkyd Resin Subjected to the High Temperature Influence

• Published in: Archives of metallurgy and materials 2016-12, Vol.61 (4), p.2171-2176
• Main Authors: Holtzer, M., Dańko, R., Żymankowska-Kumon, S., Kubecki, M., Bobrowski, A.
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Alcohol; Alkyd resins; binding; BTEX; Castings; Chromatography; Decomposition; Ethylbenzene; Foundry sands; Furfuryl alcohol; Gas chromatography; GC/MS; Hazardous materials; High temperature; Laboratories; Mass spectrometry; Molding (process); moulding sand; Organic binders; Phenols; Polycyclic aromatic hydrocarbons; Qualitative analysis; Resins; Scientific imaging; Synthetic resins; thermal analysis; Thermal decomposition; Toluene; Xylene
• ISSN: 2300-1909; 1733-3490; 2300-1909
• DOI: 10.1515/amm-2016-0346

Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. These resins in their initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin, under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylbenzene, xylene), and also polycyclic aromatic hydrocarbons (PAHs) can be formed and released. The aim of the study was the development of the method, selection of analytical methods and the determination of optimal conditions of formation compounds from the BTEX and PAHs group. Investigations were carried out in the specially designed set up for the thermal decomposition of organic substances in a temperature range: 500 – 1 300°C at the laboratory scale. The object for testing was alkyd resin applied as a binding material for moulding sands. The qualitative and quantitative analyses of compounds were performed by means of the gas chromatography coupled with the mass spectrometry (GC/MS).