Adsorptive Removal of Bisphenol A by Polyethylene Meshes Grafted with an Amino Group-Containing Monomer, 2-(Dimethylamino)ethyl Methacrylate

• Published in: Physchem 2024-10, Vol.4 (4), p.431-446
• Main Authors: Yamada, Kazunori, Terada, Saori, Yamamoto, Rena, Anh, Dương Cẩm, Naitou, Takaya, Yamamoto, Sakura
• Format: Article
• Language: English
• Subjects: 2-(dimethylamino)ethyl methacrylate; Activated carbon; Adsorbents; Adsorption; Bisphenol A; Composite materials; Epoxy resins; Food; grafting; Investigations; kinetic analysis; Organic chemicals; Polyethylene; Polymers; Water treatment
• ISSN: 2673-7167; 2673-7167
• DOI: 10.3390/physchem4040030

The adsorptive removal of Bisphenol A (BPA) with the PE meshes photografted with 2-(dimethylamino)ethyl methacrylate (DMAEMA) was performed by varying the grafted amount, pH value, BPA concentration, and temperature, and the adsorption performance was correlated by the equilibrium, kinetic, and isotherm models. In addition, the regeneration of DMAEMA-grafted PE (PE-g-PDMAEMA) meshes was discussed from the repetitive adsorption/desorption process. The adsorption capacity had the maximum value at the grafted amount of 2.6 mmol/g and at the initial pH value of 8.0. The increase in the protonation of dimethylamino groups on grafted PDMAEMA chains and the dissociation of phenol groups of BPA present in the outer solution during the adsorption process results in the increase in BPA adsorption. The adsorption process followed the pseudo second-order equation. The BPA adsorption was enhanced by increasing the BPA concentration and the equilibrium data fit to Langmuir equation. The adsorption capacity stayed almost constant with the increase in the temperature, whereas the k2 value increased against the temperature. These results comprehensively emphasized that BPA adsorption occurred through the chemical interaction or ionic bonding of a BPA anion to a terminal protonated dimethylamino group. Desorption of BPA increased by increasing the NaOH concentration and BPA was entirely desorbed at more than 20 mM. The cycle of adsorption at pH 8.0 and desorption in a NaOH solution at 100 mM was repeated five times without loss or structural damage. These results indicate PE-g-PDMAEMA meshes can be used as a regenerative adsorbent for BPA removal from aqueous medium.