Structural Features, Chemical Diversity, and Physical Properties of Microporous Sodalite-Type Materials: A Review

This review contains data on a wide class of microporous materials with frameworks belonging to the sodalite topological type. Various methods for the synthesis of these materials, their structural and crystal chemical features, as well as physical and chemical properties are discussed. Specific pro...

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Bibliographic Details
Published in:International journal of molecular sciences 2024-09, Vol.25 (18), p.10218
Main Authors: Chukanov, Nikita V, Aksenov, Sergey M
Format: Article
Language:English
Subjects:
Chemical properties
crystal chemistry
Crystals
ion exchange
Mechanical properties
Minerals
Morphology
Raw materials
Review
Sodalite
sodalite-related materials
Sodium
sorption
Structure
synthesis
Water purification
Zeolites
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Summary:This review contains data on a wide class of microporous materials with frameworks belonging to the sodalite topological type. Various methods for the synthesis of these materials, their structural and crystal chemical features, as well as physical and chemical properties are discussed. Specific properties of sodalite-related materials make it possible to consider they as thermally stable ionic conductors, catalysts and catalyst carriers, sorbents, ion exchangers for water purification, matrices for the immobilization of radionuclides and heavy metals, hydrogen and methane storage, and stabilization of chromophores and phosphors. It has been shown that the diversity of properties of sodalite-type materials is associated with the chemical diversity of their frameworks and extra-framework components, as well as with the high elasticity of the framework.
ISSN:1422-0067
1661-6596
1422-0067
DOI:10.3390/ijms251810218