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Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite
Sediment phosphorus (P) removal is crucial for the control of eutrophication, and the in-situ adsorption is an essential technique. In this study, modified maifanite (MMF) prepared by acidification, alkalization, salinization, calcination and combined modifications, respectively, were first applied...
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Published in: | Scientific reports 2018-10, Vol.8 (1), p.15619-13, Article 15619 |
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description | Sediment phosphorus (P) removal is crucial for the control of eutrophication, and the
in-situ
adsorption is an essential technique. In this study, modified maifanite (MMF) prepared by acidification, alkalization, salinization, calcination and combined modifications, respectively, were first applied to treat sediment P. The morphology and microstructure of MMF samples were characterized by X-ray fluorescence (XRF), Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM) and Brunauer-Emmett-Teller (BET). Various adsorption parameters were tested, such as dosage of maifanite, time, operation pH and temperature. The adsorption mechanisms were also investigated and discussed. Results showed that CMMF-H2.5-400 (2.5 mol/L H
2
SO
4
and calcined at 400 °C) exhibited the highest P adsorption capacity. Thus, it was selected as the
in-situ
adsorbent material to control the internal P loading. Under the optimal conditions of dynamic experiments, the adsorption rates of TP, IP, OP, Fe/Al-P and Ca-P by CMMF-H2.5-400 were 37.22%, 44.41%, 25.54%, 26.09% and 60.34%, respectively. The adsorption mechanisms analysis revealed that the adsorption of P onto CMMF-H2.5-400 mainly by ligand exchange. Results of this work indicated that the modification treatment could improve the adsorption capacity of maifanite, and CMMF-H2.5-400 could be further applied to eutrophication treatment. |
doi_str_mv | 10.1038/s41598-018-34144-w |
format | article |
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in-situ
adsorption is an essential technique. In this study, modified maifanite (MMF) prepared by acidification, alkalization, salinization, calcination and combined modifications, respectively, were first applied to treat sediment P. The morphology and microstructure of MMF samples were characterized by X-ray fluorescence (XRF), Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM) and Brunauer-Emmett-Teller (BET). Various adsorption parameters were tested, such as dosage of maifanite, time, operation pH and temperature. The adsorption mechanisms were also investigated and discussed. Results showed that CMMF-H2.5-400 (2.5 mol/L H
2
SO
4
and calcined at 400 °C) exhibited the highest P adsorption capacity. Thus, it was selected as the
in-situ
adsorbent material to control the internal P loading. Under the optimal conditions of dynamic experiments, the adsorption rates of TP, IP, OP, Fe/Al-P and Ca-P by CMMF-H2.5-400 were 37.22%, 44.41%, 25.54%, 26.09% and 60.34%, respectively. The adsorption mechanisms analysis revealed that the adsorption of P onto CMMF-H2.5-400 mainly by ligand exchange. Results of this work indicated that the modification treatment could improve the adsorption capacity of maifanite, and CMMF-H2.5-400 could be further applied to eutrophication treatment.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-018-34144-w</identifier><identifier>PMID: 30353133</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>142/136 ; 704/158/854 ; 704/172/169/896 ; Acidification ; Adsorption ; Adsorption Capacity ; Adsorption Rate ; Combined Modifications ; Eutrophication ; Fourier analysis ; Fourier Transform Infrared (FTIR) ; Fourier transforms ; Humanities and Social Sciences ; Modification Treatment ; multidisciplinary ; Phosphorus ; Phosphorus removal ; Salinization ; Scanning electron microscopy ; Science ; Science (multidisciplinary) ; Sediments ; Sulfuric acid ; X-ray diffraction ; X-ray fluorescence</subject><ispartof>Scientific reports, 2018-10, Vol.8 (1), p.15619-13, Article 15619</ispartof><rights>The Author(s) 2018</rights><rights>2018. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c643t-cc03970aee95ca1c6db8bedfb458c7fe07c5415b031e435e1662846ee32ba1f33</citedby><cites>FETCH-LOGICAL-c643t-cc03970aee95ca1c6db8bedfb458c7fe07c5415b031e435e1662846ee32ba1f33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2124454192/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2124454192?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25752,27923,27924,37011,37012,44589,53790,53792,74997</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30353133$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Zisen</creatorcontrib><creatorcontrib>Zhang, Yi</creatorcontrib><creatorcontrib>Han, Fan</creatorcontrib><creatorcontrib>Yan, Pan</creatorcontrib><creatorcontrib>Liu, Biyun</creatorcontrib><creatorcontrib>Zhou, Qiaohong</creatorcontrib><creatorcontrib>Min, Fenli</creatorcontrib><creatorcontrib>He, Feng</creatorcontrib><creatorcontrib>Wu, Zhenbin</creatorcontrib><title>Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Sediment phosphorus (P) removal is crucial for the control of eutrophication, and the
in-situ
adsorption is an essential technique. In this study, modified maifanite (MMF) prepared by acidification, alkalization, salinization, calcination and combined modifications, respectively, were first applied to treat sediment P. The morphology and microstructure of MMF samples were characterized by X-ray fluorescence (XRF), Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM) and Brunauer-Emmett-Teller (BET). Various adsorption parameters were tested, such as dosage of maifanite, time, operation pH and temperature. The adsorption mechanisms were also investigated and discussed. Results showed that CMMF-H2.5-400 (2.5 mol/L H
2
SO
4
and calcined at 400 °C) exhibited the highest P adsorption capacity. Thus, it was selected as the
in-situ
adsorbent material to control the internal P loading. Under the optimal conditions of dynamic experiments, the adsorption rates of TP, IP, OP, Fe/Al-P and Ca-P by CMMF-H2.5-400 were 37.22%, 44.41%, 25.54%, 26.09% and 60.34%, respectively. The adsorption mechanisms analysis revealed that the adsorption of P onto CMMF-H2.5-400 mainly by ligand exchange. Results of this work indicated that the modification treatment could improve the adsorption capacity of maifanite, and CMMF-H2.5-400 could be further applied to eutrophication treatment.</description><subject>142/136</subject><subject>704/158/854</subject><subject>704/172/169/896</subject><subject>Acidification</subject><subject>Adsorption</subject><subject>Adsorption Capacity</subject><subject>Adsorption Rate</subject><subject>Combined Modifications</subject><subject>Eutrophication</subject><subject>Fourier analysis</subject><subject>Fourier Transform Infrared (FTIR)</subject><subject>Fourier transforms</subject><subject>Humanities and Social Sciences</subject><subject>Modification Treatment</subject><subject>multidisciplinary</subject><subject>Phosphorus</subject><subject>Phosphorus removal</subject><subject>Salinization</subject><subject>Scanning electron microscopy</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Sediments</subject><subject>Sulfuric acid</subject><subject>X-ray diffraction</subject><subject>X-ray fluorescence</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNp9Uk1v1DAQjRCIVkv_AAcUiQuXgO2xk_iChCo-VqrEBc6WP8a7XiXxYiet-u_xNqW0HLBseeR58-x5flX1mpL3lED_IXMqZN8Q2jfAKefNzbPqnBEuGgaMPX8Un1UXOR9IGYJJTuXL6gwICKAA55XZTteY57DTc4hTXea8x1q7HNNxPfH1cR9zWWnJdZhqPQy1T9qesrlEcawzujDiNNfmth6jCz6gq0cdvJ7CjK-qF14PGS_u903188vnH5ffmqvvX7eXn64a23KYG2sJyI5oRCmsprZ1pjfovOGit51H0llRejYEKHIQSNuW9bxFBGY09QCbarvyuqgP6pjCqNOtijqou4OYdkqnOdgBVed7b5wTha0o0oNpDfcSgffUOARZuD6uXMfFjOhsaS7p4Qnp08wU9moXr1VLpYQi7aZ6d0-Q4q-lKKzGkC0Og54wLlkxygSQnpGuQN_-Az3EJU1FqhOK89K1ZAXFVpRNMeeE_uExlKiTI9TqCFUcoe4coW5K0ZvHbTyU_Pn_AoAVkEtq2mH6e_d_aH8DOLvDqw</recordid><startdate>20181023</startdate><enddate>20181023</enddate><creator>Liu, Zisen</creator><creator>Zhang, Yi</creator><creator>Han, Fan</creator><creator>Yan, Pan</creator><creator>Liu, Biyun</creator><creator>Zhou, Qiaohong</creator><creator>Min, Fenli</creator><creator>He, Feng</creator><creator>Wu, Zhenbin</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><general>Nature Portfolio</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope></search><sort><creationdate>20181023</creationdate><title>Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite</title><author>Liu, Zisen ; 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in-situ
adsorption is an essential technique. In this study, modified maifanite (MMF) prepared by acidification, alkalization, salinization, calcination and combined modifications, respectively, were first applied to treat sediment P. The morphology and microstructure of MMF samples were characterized by X-ray fluorescence (XRF), Fourier transform infrared (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM) and Brunauer-Emmett-Teller (BET). Various adsorption parameters were tested, such as dosage of maifanite, time, operation pH and temperature. The adsorption mechanisms were also investigated and discussed. Results showed that CMMF-H2.5-400 (2.5 mol/L H
2
SO
4
and calcined at 400 °C) exhibited the highest P adsorption capacity. Thus, it was selected as the
in-situ
adsorbent material to control the internal P loading. Under the optimal conditions of dynamic experiments, the adsorption rates of TP, IP, OP, Fe/Al-P and Ca-P by CMMF-H2.5-400 were 37.22%, 44.41%, 25.54%, 26.09% and 60.34%, respectively. The adsorption mechanisms analysis revealed that the adsorption of P onto CMMF-H2.5-400 mainly by ligand exchange. Results of this work indicated that the modification treatment could improve the adsorption capacity of maifanite, and CMMF-H2.5-400 could be further applied to eutrophication treatment.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>30353133</pmid><doi>10.1038/s41598-018-34144-w</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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subjects | 142/136 704/158/854 704/172/169/896 Acidification Adsorption Adsorption Capacity Adsorption Rate Combined Modifications Eutrophication Fourier analysis Fourier Transform Infrared (FTIR) Fourier transforms Humanities and Social Sciences Modification Treatment multidisciplinary Phosphorus Phosphorus removal Salinization Scanning electron microscopy Science Science (multidisciplinary) Sediments Sulfuric acid X-ray diffraction X-ray fluorescence |
title | Investigation on the adsorption of phosphorus in all fractions from sediment by modified maifanite |
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