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Red-Emitting Carbon Dots as a Dual Sensor for In3+ and Pd2+ in Water
We have demonstrated the synthesis, characterization, and application of nitrogen-doped red-emitting carbon dots (NRCDs) for dual sensing of indium (In3+) and palladium (Pd2+) in water. The detection of In3+ was associated with “turn-on” fluorescence response with a red shift, while in the presence...
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Published in: | ACS omega 2020-04, Vol.5 (14), p.8362-8372 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Online Access: | Get full text |
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Summary: | We have demonstrated the synthesis, characterization, and application of nitrogen-doped red-emitting carbon dots (NRCDs) for dual sensing of indium (In3+) and palladium (Pd2+) in water. The detection of In3+ was associated with “turn-on” fluorescence response with a red shift, while in the presence of Pd2+, the fluorescence intensity of NRCDs was quenched to show a “turn-off” response. The interaction of NRCDs with the metal ions was investigated using 1H nuclear magnetic resonance and Fourier-transform infrared spectroscopy studies. The synthesized nanoprobes possessed good biocompatibility and photostability and were found to be suitable candidates for bioimaging due to their emission profiles in the near-infrared (NIR) window. Applicability of the as-prepared NRCDs was demonstrated in the NIR region when they were loaded in vesicle membranes with and without cations and subjected to confocal imaging successfully. |
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ISSN: | 2470-1343 2470-1343 |
DOI: | 10.1021/acsomega.0c00883 |