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Sputtered thin film deposited laser induced graphene based novel micro-supercapacitor device for energy storage application
Pioneering flexible micro-supercapacitors, designed for exceptional energy and power density, transcend conventional storage limitations. Interdigitated electrodes (IDEs) based on laser-induced graphene (LIG), augmented with metal-oxide modifiers, harness synergies with layered graphene to achieve s...
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Published in: | Scientific reports 2024-07, Vol.14 (1), p.16289-12, Article 16289 |
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creator | Sain, Sourav Chowdhury, Suman Maity, Sayantan Maity, Gurupada Roy, Susanta Sinha |
description | Pioneering flexible micro-supercapacitors, designed for exceptional energy and power density, transcend conventional storage limitations. Interdigitated electrodes (IDEs) based on laser-induced graphene (LIG), augmented with metal-oxide modifiers, harness synergies with layered graphene to achieve superior capacitance. This study presents a novel one-step process for sputtered plasma deposition of HfO
2
, resulting in enhanced supercapacitance performance. Introducing LIG-HfO
2
micro-supercapacitor (MSC) devices with varied oxygen flow rates further boosts supercapacitance performance by introducing oxygen functional groups. FESEM investigations demonstrate uniform coating of HfO
2
on LIG fibers through sputtering. Specific capacitance measurements reveal 6.4 mF/cm
2
at 5 mV/s and 4.5 mF/cm
2
at a current density of 0.04 mA/cm
2
. The LIG-HfO
2
devices exhibit outstanding supercapacitor performance, boasting at least a fourfold increase over pristine LIG. Moreover, stability testing indicates a high retention rate of 97% over 5000 cycles, ensuring practical real-time applications. |
doi_str_mv | 10.1038/s41598-024-62192-y |
format | article |
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2
, resulting in enhanced supercapacitance performance. Introducing LIG-HfO
2
micro-supercapacitor (MSC) devices with varied oxygen flow rates further boosts supercapacitance performance by introducing oxygen functional groups. FESEM investigations demonstrate uniform coating of HfO
2
on LIG fibers through sputtering. Specific capacitance measurements reveal 6.4 mF/cm
2
at 5 mV/s and 4.5 mF/cm
2
at a current density of 0.04 mA/cm
2
. The LIG-HfO
2
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2
, resulting in enhanced supercapacitance performance. Introducing LIG-HfO
2
micro-supercapacitor (MSC) devices with varied oxygen flow rates further boosts supercapacitance performance by introducing oxygen functional groups. FESEM investigations demonstrate uniform coating of HfO
2
on LIG fibers through sputtering. Specific capacitance measurements reveal 6.4 mF/cm
2
at 5 mV/s and 4.5 mF/cm
2
at a current density of 0.04 mA/cm
2
. The LIG-HfO
2
devices exhibit outstanding supercapacitor performance, boasting at least a fourfold increase over pristine LIG. Moreover, stability testing indicates a high retention rate of 97% over 5000 cycles, ensuring practical real-time applications.</description><subject>639/301/299/161</subject><subject>639/4077/4079/4105</subject><subject>Capacitance</subject><subject>Composite materials</subject><subject>Ductility</subject><subject>Electrodes</subject><subject>Energy storage</subject><subject>Flexible electrodes</subject><subject>Flow rates</subject><subject>Graphene</subject><subject>Hafnium oxide (HfO2)</subject><subject>Humanities and Social Sciences</subject><subject>Laser Induced Graphene (LIG)</subject><subject>Lasers</subject><subject>Metal oxides</subject><subject>Metals</subject><subject>Micro supercapacitor devices (MSC)</subject><subject>multidisciplinary</subject><subject>Oxidation</subject><subject>Polyvinyl alcohol</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Sputtering</subject><subject>Thin films</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNp9kk1vFSEUhidGY5vaP-DCkLhxM8rXMLAypvGjSRMX6powfMzlZi6MwNzkxj8v06m1dSEbDof3PMDhbZqXCL5FkPB3maJO8BZi2jKMBG5PT5pzDGnXYoLx0wfxWXOZ8x7W0WFBkXjenBEBoWCQnTe_vs1LKTZZA8rOB-D8dADGzjH7UnOTyjYBH8yi62pMat7ZYMFQ0waEeLQTOHidYpuX2SatZqV9iakSjl5b4GpY9Wk8gVzTarRAzfPktSo-hhfNM6embC_v5ovmx6eP36--tDdfP19ffbhpNcW4tJwhDp3mdCA97XrSDQNjrFeOGiIEo5yZnjHnOoJ6iAzTnOkOG0eo7VivDblorjeuiWov5-QPKp1kVF7eJmIapUrF68lKvjZJV7zpHa213DHBzEA05QjRAVbW-401L8PBGm1DSWp6BH28E_xOjvEoEcIdgmglvLkjpPhzsbnIg8_aTpMKNi5ZEsgRFoj3q_T1P9J9XFKovVpVkIuOU1xVeFPVf8g5WXd_GwTl6hW5eUVWr8hbr8hTLXr18B33JX-cUQVkE-S6FUab_p79H-xvjjPL3g</recordid><startdate>20240715</startdate><enddate>20240715</enddate><creator>Sain, Sourav</creator><creator>Chowdhury, Suman</creator><creator>Maity, Sayantan</creator><creator>Maity, Gurupada</creator><creator>Roy, Susanta Sinha</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><general>Nature Portfolio</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope></search><sort><creationdate>20240715</creationdate><title>Sputtered thin film deposited laser induced graphene based novel micro-supercapacitor device for energy storage application</title><author>Sain, Sourav ; 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Interdigitated electrodes (IDEs) based on laser-induced graphene (LIG), augmented with metal-oxide modifiers, harness synergies with layered graphene to achieve superior capacitance. This study presents a novel one-step process for sputtered plasma deposition of HfO
2
, resulting in enhanced supercapacitance performance. Introducing LIG-HfO
2
micro-supercapacitor (MSC) devices with varied oxygen flow rates further boosts supercapacitance performance by introducing oxygen functional groups. FESEM investigations demonstrate uniform coating of HfO
2
on LIG fibers through sputtering. Specific capacitance measurements reveal 6.4 mF/cm
2
at 5 mV/s and 4.5 mF/cm
2
at a current density of 0.04 mA/cm
2
. The LIG-HfO
2
devices exhibit outstanding supercapacitor performance, boasting at least a fourfold increase over pristine LIG. Moreover, stability testing indicates a high retention rate of 97% over 5000 cycles, ensuring practical real-time applications.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>39009606</pmid><doi>10.1038/s41598-024-62192-y</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record> |
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source | Publicly Available Content Database (Proquest) (PQ_SDU_P3); Full-Text Journals in Chemistry (Open access); PubMed Central; Springer Nature - nature.com Journals - Fully Open Access |
subjects | 639/301/299/161 639/4077/4079/4105 Capacitance Composite materials Ductility Electrodes Energy storage Flexible electrodes Flow rates Graphene Hafnium oxide (HfO2) Humanities and Social Sciences Laser Induced Graphene (LIG) Lasers Metal oxides Metals Micro supercapacitor devices (MSC) multidisciplinary Oxidation Polyvinyl alcohol Science Science (multidisciplinary) Sputtering Thin films |
title | Sputtered thin film deposited laser induced graphene based novel micro-supercapacitor device for energy storage application |
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