Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]

In the title compound, {[Cu(C(18)H(12)N(6))]NO(3)·H(2)O}(n), the Cu(I) ion is coordinated by three N atoms [Cu-N 1.962 (3)-2.019 (3) Å] from three 2,4,6-tri-4-pyridyl-1,3,5-triazine (L) ligands. Each L ligand bridges three Cu(I) atoms, generating a positively charged three-dimensional polymeric netw...

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Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-04, Vol.67 (Pt 4), p.m515-m515
Main Authors: Feng, Miao, Tian, Hui-Juan, Mi, Huai-Feng, Hu, Tong-Liang
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:In the title compound, {[Cu(C(18)H(12)N(6))]NO(3)·H(2)O}(n), the Cu(I) ion is coordinated by three N atoms [Cu-N 1.962 (3)-2.019 (3) Å] from three 2,4,6-tri-4-pyridyl-1,3,5-triazine (L) ligands. Each L ligand bridges three Cu(I) atoms, generating a positively charged three-dimensional polymeric network with voids propagated along the b axis. These voids are filled with NO(3) (-) anions with a shortest Cu⋯O distance of 2.645 (3) Å and water mol-ecules, which are linked into negatively charged helical chains via inter-molecular O-H⋯O hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811011445