trans -Dichloridobis(dimethyl sulfoxide-κ O )bis(4-fluorobenzyl-κ C 1 )tin(IV): crystal structure and Hirshfeld surface analysis

The Sn IV atom in the title diorganotin compound, [Sn(C 7 H 6 F) 2 Cl 2 (C 2 H 6 OS) 2 ], is located on a centre of inversion, resulting in the C 2 Cl 2 O 2 donor set having an all- trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C—H...F, C...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2017-05, Vol.73 (5), p.667-672
Main Authors: Amin, Nur Adibah Binti Mohd, Hussen, Rusnah Syahila Duali, Lee, See Mun, Halcovitch, Nathan R., Jotani, Mukesh M., Tiekink, Edward R. T.
Format: Article
Language:English
Subjects:
crystal structure
C—H...F interactions
Hirshfeld surface analysis
organotin
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Summary:The Sn IV atom in the title diorganotin compound, [Sn(C 7 H 6 F) 2 Cl 2 (C 2 H 6 OS) 2 ], is located on a centre of inversion, resulting in the C 2 Cl 2 O 2 donor set having an all- trans disposition of like atoms. The coordination geometry approximates an octahedron. The crystal features C—H...F, C—H...Cl and C—H...π interactions, giving rise to a three-dimensional network. The respective influences of the Cl...H/H...Cl and F...H/H...F contacts to the molecular packing are clearly evident from the analysis of the Hirshfeld surface.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989017005072