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Photocatalytic Reduction of Hexavalent Chromium with Nanosized TiO2 in Presence of Formic Acid
Nanosized titanium dioxide (TiO2) nanoparticles were used for the photocatalytic reduction of hexavalent chromium in the presence of formic acid. The photoreduction of Cr(VI) in the absence of formic acid was quite slow. When formic acid was added in the chromium solution as the hole scavenger, a ra...
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Published in: | ChemEngineering 2019-06, Vol.3 (2), p.33 |
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creator | Islam, Jahida Binte Furukawa, Mai Tateishi, Ikki Katsumata, Hideyuki Kaneco, Satoshi |
description | Nanosized titanium dioxide (TiO2) nanoparticles were used for the photocatalytic reduction of hexavalent chromium in the presence of formic acid. The photoreduction of Cr(VI) in the absence of formic acid was quite slow. When formic acid was added in the chromium solution as the hole scavenger, a rapid photocatalytic reduction of Cr(VI) was observed, owing to the consumption of hole and the acceleration of the oxidation reaction. Furthermore, three commercial TiO2 nanoparticles (AEROXIDE® P25; Ishihara Sangyo ST-01; FUJIFILM Wako Pure Chemical Corp.) were evaluated for the photoactivity of reduction of Cr(VI). |
doi_str_mv | 10.3390/chemengineering3020033 |
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The photoreduction of Cr(VI) in the absence of formic acid was quite slow. When formic acid was added in the chromium solution as the hole scavenger, a rapid photocatalytic reduction of Cr(VI) was observed, owing to the consumption of hole and the acceleration of the oxidation reaction. Furthermore, three commercial TiO2 nanoparticles (AEROXIDE® P25; Ishihara Sangyo ST-01; FUJIFILM Wako Pure Chemical Corp.) were evaluated for the photoactivity of reduction of Cr(VI).</description><identifier>ISSN: 2305-7084</identifier><identifier>EISSN: 2305-7084</identifier><identifier>DOI: 10.3390/chemengineering3020033</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Acceleration ; Aqueous solutions ; Chemical engineering ; Chromium ; Formic acid ; Hexavalent chromium ; hole scavenger ; Nanoparticles ; nanosized TiO2 ; Oxidation ; Particle size ; Photocatalysis ; photocatalytic reduction ; Reduction ; Titanium dioxide</subject><ispartof>ChemEngineering, 2019-06, Vol.3 (2), p.33</ispartof><rights>2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). 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The photoreduction of Cr(VI) in the absence of formic acid was quite slow. When formic acid was added in the chromium solution as the hole scavenger, a rapid photocatalytic reduction of Cr(VI) was observed, owing to the consumption of hole and the acceleration of the oxidation reaction. Furthermore, three commercial TiO2 nanoparticles (AEROXIDE® P25; Ishihara Sangyo ST-01; FUJIFILM Wako Pure Chemical Corp.) were evaluated for the photoactivity of reduction of Cr(VI).</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/chemengineering3020033</doi><oa>free_for_read</oa></addata></record> |
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subjects | Acceleration Aqueous solutions Chemical engineering Chromium Formic acid Hexavalent chromium hole scavenger Nanoparticles nanosized TiO2 Oxidation Particle size Photocatalysis photocatalytic reduction Reduction Titanium dioxide |
title | Photocatalytic Reduction of Hexavalent Chromium with Nanosized TiO2 in Presence of Formic Acid |
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