Enhancement of Piezoelectricity by Novel Poling Method of the Rare‐Earth Modified BiFeO3–BaTiO3 Lead‐Free Ceramics

• Published in: Advanced electronic materials 2023-05, Vol.9 (5), p.n/a
• Main Authors: Habib, Muhammad, Zhou, Xuefan, Tang, Lin, Xue, Guoliang, Rahman, Attaur, Akram, Fazli, Zhang, Dou
• Format: Article
• Language: English
• Subjects: Actuators; Barium titanates; BiFeO 3–BaTiO 3; Crystal structure; Curie temperature; donor‐doping; Doping; Hysteresis; lead‐free piezoceramics; magnetic poling; Piezoelectric ceramics; Piezoelectricity; rare‐earth; Reproducibility; Single crystals; Spectrum analysis
• ISSN: 2199-160X; 2199-160X
• DOI: 10.1002/aelm.202201210

In piezoceramics, the Curie temperature (TC) and piezoelectric coefficient (d33) are often inversely proportional, so it is very difficult to optimize high piezoelectricity and TC simultaneously. In addition, the high and temperature‐insensitive piezoelectric strain coefficient (d33*) with small hysteresis is also a longstanding obstacle in the development of lead‐free ceramics. In this work, a facile approach of donor doping strategy is adopted to replace Ba2+ with Yb3+, Y3+, Sm3+, and Nd3+ as a result, a high TC of 450 °C and outstanding d33 of 422–436 pC N−1 is achieved by a novel magnetic poling method. Thermally‐stable and outstanding piezoelectric strain performance (d33* ≈ 520–550 pm V−1 and ΔST ≈ 10%) with small strain hysteresis (H < 20%) results are highly encourageable in lead‐free ceramics. The main factors contributing to high piezoelectricity are the morphotropic phase boundary, suppression of defect charges by donor doping, thermal quenching, mesoscale nanodomain size, and novel poling method. The excellent piezoelectric performance and high TC of this work are superior to those of state‐of‐the‐art piezoceramics. The synergistic approaches of compositional design strategy and novel poling process in this work are highly beneficial for temperature‐insensitive piezoelectric sensor and actuator applications. Normally, the piezoelectric constant (d33) and Curie temperature (TC) are inversely proportional. In this work, simultaneously high TC of 450 °C and excellent piezoelectric performance (d33 ≈ 436 ± 5 pC N−1) are achieved in lead‐free BiFeO3–BaTiO3 ceramics. This high d33 value is obtained by applying a novel poling method inside a strong magnetic field.