Elevating Supercapacitor Performance of Co3O4-g-C3N4 Nanocomposites Fabricated via the Hydrothermal Method

• Published in: Micromachines (Basel) 2024-03, Vol.15 (3), p.414
• Main Authors: Yewale, Manesh A., Kumar, Vineet, Teli, Aviraj M., Beknalkar, Sonali A., Nakate, Umesh T., Shin, Dong-Kil
• Format: Article
• Language: English
• Subjects: Activated carbon; Alternative energy sources; Aqueous electrolytes; Asymmetry; Carbon nitride; Co3O4 nanoparticles; Cobalt; Cobalt oxides; Composite materials; Electrochemical analysis; Electrodes; Electrolytes; Electrons; Energy resources; Energy storage; graphic carbon nitride (g-C3N4); Metal oxides; Nanocomposites; Nanoparticles; Nitrogen; Polyvinyl alcohol; Potassium hydroxides; Renewable resources; Spectrum analysis; Storage capacity; supercapacitor; Supercapacitors
• ISSN: 2072-666X; 2072-666X
• DOI: 10.3390/mi15030414

The hydrothermal method has been utilized to synthesize graphitic carbon nitride (g-C3N4) polymers and cobalt oxide composites effectively. The weight percentage of g-C3N4 nanoparticles influenced the electrochemical performance of the Co3O4-g-C3N4 composite. In an aqueous electrolyte, the Co3O4-g-C3N4 composite electrode, produced with 150 mg of g-C3N4 nanoparticles, revealed remarkable electrochemical performance. With an increase in the weight percentage of g-C3N4 nanoparticles, the capacitive contribution of the Co3O4-g-C3N4 composite electrode increased. The Co3O4-g-C3N4-150 mg composite electrode shows a specific capacitance of 198 F/g. The optimized electrode, activated carbon, and polyvinyl alcohol gel with potassium hydroxide were used to develop an asymmetric supercapacitor. At a current density of 5 mA/cm2, the asymmetric supercapacitor demonstrated exceptional energy storage capacity with remarkable energy density and power density. The device retained great capacity over 6k galvanostatic charge–discharge (GCD) cycles, with no rise in series resistance following cyclic stability. The columbic efficiency of the asymmetric supercapacitor was likewise high.