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A cuboidal [Cu 4 (SO 4 ) 4 ] structure supported by β-picoline ligands
The solid-state structure of the cobalt-β-picoline-sulfate complex tetra-μ -sulfato-tetra-kis-[bis-(3-methyl-pyridine)-cobalt(II)], [Co (SO ) (C H N) ], is reported. The tetra-meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube...
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| Published in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2022-02, Vol.78 (Pt 2), p.108-110 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c432t-da1bfa7cffaa07c35083feec2a673bd845480c6ab61301496f15b6664736dda23 |
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| cites | cdi_FETCH-LOGICAL-c432t-da1bfa7cffaa07c35083feec2a673bd845480c6ab61301496f15b6664736dda23 |
| container_end_page | 110 |
| container_issue | Pt 2 |
| container_start_page | 108 |
| container_title | Acta crystallographica. Section E, Crystallographic communications |
| container_volume | 78 |
| creator | Park, Ava M Golen, James A Manke, David R |
| description | The solid-state structure of the cobalt-β-picoline-sulfate complex tetra-μ
-sulfato-tetra-kis-[bis-(3-methyl-pyridine)-cobalt(II)], [Co
(SO
)
(C
H
N)
], is reported. The tetra-meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube vertices. The cobalt corners are each capped with two β-picoline ligands. The sulfate anions adopt a rare [3.2110] bridging motif, and the cuboidal cluster is unprecedented in coordination chemistry. |
| doi_str_mv | 10.1107/S2056989022000780 |
| format | article |
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-sulfato-tetra-kis-[bis-(3-methyl-pyridine)-cobalt(II)], [Co
(SO
)
(C
H
N)
], is reported. The tetra-meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube vertices. The cobalt corners are each capped with two β-picoline ligands. The sulfate anions adopt a rare [3.2110] bridging motif, and the cuboidal cluster is unprecedented in coordination chemistry.</description><identifier>ISSN: 2056-9890</identifier><identifier>EISSN: 2056-9890</identifier><identifier>DOI: 10.1107/S2056989022000780</identifier><identifier>PMID: 35145733</identifier><language>eng</language><publisher>England: International Union of Crystallography</publisher><subject>cobalt complexes ; coordination chemistry ; crystal structure ; Jerry P. Jasinski tribute ; picoline ; sulfate ; transition metal</subject><ispartof>Acta crystallographica. Section E, Crystallographic communications, 2022-02, Vol.78 (Pt 2), p.108-110</ispartof><rights>Park et al. 2022.</rights><rights>Park et al. 2022 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c432t-da1bfa7cffaa07c35083feec2a673bd845480c6ab61301496f15b6664736dda23</citedby><cites>FETCH-LOGICAL-c432t-da1bfa7cffaa07c35083feec2a673bd845480c6ab61301496f15b6664736dda23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8819428/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8819428/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35145733$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Park, Ava M</creatorcontrib><creatorcontrib>Golen, James A</creatorcontrib><creatorcontrib>Manke, David R</creatorcontrib><title>A cuboidal [Cu 4 (SO 4 ) 4 ] structure supported by β-picoline ligands</title><title>Acta crystallographica. Section E, Crystallographic communications</title><addtitle>Acta Crystallogr E Crystallogr Commun</addtitle><description>The solid-state structure of the cobalt-β-picoline-sulfate complex tetra-μ
-sulfato-tetra-kis-[bis-(3-methyl-pyridine)-cobalt(II)], [Co
(SO
)
(C
H
N)
], is reported. The tetra-meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube vertices. The cobalt corners are each capped with two β-picoline ligands. The sulfate anions adopt a rare [3.2110] bridging motif, and the cuboidal cluster is unprecedented in coordination chemistry.</description><subject>cobalt complexes</subject><subject>coordination chemistry</subject><subject>crystal structure</subject><subject>Jerry P. Jasinski tribute</subject><subject>picoline</subject><subject>sulfate</subject><subject>transition metal</subject><issn>2056-9890</issn><issn>2056-9890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNplkc1KxDAUhYMoKqMP4Eay1EU1f03SjSCDjgPCLNSVSLj5Gyt1WtJWmNfyQXwmO46Kg4vcXE5yvoR7EDqi5IxSos7vGMlloQvCGCFEabKF9ldSttK2__R76LBtX4Y7VORc5mwX7fF86BXn-2hyiV1v69JDhR_HPRb45G421NNhPeG2S73r-hRw2zdNnbrgsV3ij_esKV1dlYuAq3IOC98eoJ0IVRsOv_cReri-uh_fZLezyXR8eZs5wVmXeaA2gnIxAhDleE40jyE4BlJx67XIhSZOgpWUD_8tZKS5lVIKxaX3wPgITddcX8OLaVL5CmlpaijNl1CnuYHUla4KRitPVUF1cJwKL6zluYgsei0BlB9mMUIXa1bT29fgXVh0CaoN6ObJonw28_rNaE0LwfQAoGuAS3XbphB_vZSYVUjmX0iD5_jvo7-On0j4J4bRi5Y</recordid><startdate>20220201</startdate><enddate>20220201</enddate><creator>Park, Ava M</creator><creator>Golen, James A</creator><creator>Manke, David R</creator><general>International Union of Crystallography</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>5PM</scope><scope>DOA</scope></search><sort><creationdate>20220201</creationdate><title>A cuboidal [Cu 4 (SO 4 ) 4 ] structure supported by β-picoline ligands</title><author>Park, Ava M ; Golen, James A ; Manke, David R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c432t-da1bfa7cffaa07c35083feec2a673bd845480c6ab61301496f15b6664736dda23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>cobalt complexes</topic><topic>coordination chemistry</topic><topic>crystal structure</topic><topic>Jerry P. Jasinski tribute</topic><topic>picoline</topic><topic>sulfate</topic><topic>transition metal</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Park, Ava M</creatorcontrib><creatorcontrib>Golen, James A</creatorcontrib><creatorcontrib>Manke, David R</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>PubMed Central (Full Participant titles)</collection><collection>Directory of Open Access Journals</collection><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Park, Ava M</au><au>Golen, James A</au><au>Manke, David R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A cuboidal [Cu 4 (SO 4 ) 4 ] structure supported by β-picoline ligands</atitle><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle><addtitle>Acta Crystallogr E Crystallogr Commun</addtitle><date>2022-02-01</date><risdate>2022</risdate><volume>78</volume><issue>Pt 2</issue><spage>108</spage><epage>110</epage><pages>108-110</pages><issn>2056-9890</issn><eissn>2056-9890</eissn><abstract>The solid-state structure of the cobalt-β-picoline-sulfate complex tetra-μ
-sulfato-tetra-kis-[bis-(3-methyl-pyridine)-cobalt(II)], [Co
(SO
)
(C
H
N)
], is reported. The tetra-meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube vertices. The cobalt corners are each capped with two β-picoline ligands. The sulfate anions adopt a rare [3.2110] bridging motif, and the cuboidal cluster is unprecedented in coordination chemistry.</abstract><cop>England</cop><pub>International Union of Crystallography</pub><pmid>35145733</pmid><doi>10.1107/S2056989022000780</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2056-9890 |
| ispartof | Acta crystallographica. Section E, Crystallographic communications, 2022-02, Vol.78 (Pt 2), p.108-110 |
| issn | 2056-9890 2056-9890 |
| language | eng |
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| source | PubMed Central |
| subjects | cobalt complexes coordination chemistry crystal structure Jerry P. Jasinski tribute picoline sulfate transition metal |
| title | A cuboidal [Cu 4 (SO 4 ) 4 ] structure supported by β-picoline ligands |
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