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Preparation of Boron Nitride Nanoplatelets via Amino Acid Assisted Ball Milling: Towards Thermal Conductivity Application
Hexagonal boron nitride nanoplatelets (BNNPs) have attracted widespread attention due to their unique physical properties and their peeling from the base material. Mechanical exfoliation is a simple, scalable approach to produce single-layer or few-layer BNNPs. In this work, two amino acid grafted b...
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| Published in: | Nanomaterials (Basel, Switzerland) Switzerland), 2020-08, Vol.10 (9), p.1652 |
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| Main Authors: | , , , , , , |
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| container_issue | 9 |
| container_start_page | 1652 |
| container_title | Nanomaterials (Basel, Switzerland) |
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| creator | Yang, Nan Ji, Haifeng Jiang, Xiaoxia Qu, Xiongwei Zhang, Xiaojie Zhang, Yue Liu, Binyuan |
| description | Hexagonal boron nitride nanoplatelets (BNNPs) have attracted widespread attention due to their unique physical properties and their peeling from the base material. Mechanical exfoliation is a simple, scalable approach to produce single-layer or few-layer BNNPs. In this work, two amino acid grafted boron nitride nanoplatelets, Lys@BNNP and Glu@BNNP, were successfully prepared via ball milling of h-BN with L-Lysine and L-Glutamic acid, respectively. It was found that the dispersion state of Lys@BNNP and Glu@BNNP in water had been effectively stabilized due to the introduction of amino acid moieties which contained a hydrophilic carboxyl group. PVA hydrogel composites with Lys@BNNP and Glu@BNNP as functional fillers were constructed and extensively studied. With 11.3 wt% Lys@BNNP incorporated, the thermal conductivity of Lys@BNNP/PVA hydrogel composite was up to 0.91 W m−1K−1, increased by 78%, comparing to the neat PVA hydrogel. Meanwhile, the mechanical and self-healing properties of the composites were simultaneously largely enhanced. |
| doi_str_mv | 10.3390/nano10091652 |
| format | article |
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Mechanical exfoliation is a simple, scalable approach to produce single-layer or few-layer BNNPs. In this work, two amino acid grafted boron nitride nanoplatelets, Lys@BNNP and Glu@BNNP, were successfully prepared via ball milling of h-BN with L-Lysine and L-Glutamic acid, respectively. It was found that the dispersion state of Lys@BNNP and Glu@BNNP in water had been effectively stabilized due to the introduction of amino acid moieties which contained a hydrophilic carboxyl group. PVA hydrogel composites with Lys@BNNP and Glu@BNNP as functional fillers were constructed and extensively studied. With 11.3 wt% Lys@BNNP incorporated, the thermal conductivity of Lys@BNNP/PVA hydrogel composite was up to 0.91 W m−1K−1, increased by 78%, comparing to the neat PVA hydrogel. Meanwhile, the mechanical and self-healing properties of the composites were simultaneously largely enhanced.</description><identifier>ISSN: 2079-4991</identifier><identifier>EISSN: 2079-4991</identifier><identifier>DOI: 10.3390/nano10091652</identifier><identifier>PMID: 32842698</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Amino acids ; Aqueous solutions ; Ball milling ; Boron ; Boron nitride ; Carbon ; Carboxyl group ; Communication ; Composite materials ; Ethanol ; Experiments ; Fillers ; Fourier transforms ; Glutamic acid ; Graphene ; Heat conductivity ; Heat transfer ; hexagonal boron nitride nanoplatelets ; Hydrogels ; Lysine ; mechanical exfoliation ; Mechanical properties ; Physical properties ; Polymers ; Reagents ; Self healing materials ; self-healing ; Spectrum analysis ; Thermal conductivity</subject><ispartof>Nanomaterials (Basel, Switzerland), 2020-08, Vol.10 (9), p.1652</ispartof><rights>2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). 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Mechanical exfoliation is a simple, scalable approach to produce single-layer or few-layer BNNPs. In this work, two amino acid grafted boron nitride nanoplatelets, Lys@BNNP and Glu@BNNP, were successfully prepared via ball milling of h-BN with L-Lysine and L-Glutamic acid, respectively. It was found that the dispersion state of Lys@BNNP and Glu@BNNP in water had been effectively stabilized due to the introduction of amino acid moieties which contained a hydrophilic carboxyl group. PVA hydrogel composites with Lys@BNNP and Glu@BNNP as functional fillers were constructed and extensively studied. With 11.3 wt% Lys@BNNP incorporated, the thermal conductivity of Lys@BNNP/PVA hydrogel composite was up to 0.91 W m−1K−1, increased by 78%, comparing to the neat PVA hydrogel. Meanwhile, the mechanical and self-healing properties of the composites were simultaneously largely enhanced.</description><subject>Amino acids</subject><subject>Aqueous solutions</subject><subject>Ball milling</subject><subject>Boron</subject><subject>Boron nitride</subject><subject>Carbon</subject><subject>Carboxyl group</subject><subject>Communication</subject><subject>Composite materials</subject><subject>Ethanol</subject><subject>Experiments</subject><subject>Fillers</subject><subject>Fourier transforms</subject><subject>Glutamic acid</subject><subject>Graphene</subject><subject>Heat conductivity</subject><subject>Heat transfer</subject><subject>hexagonal boron nitride nanoplatelets</subject><subject>Hydrogels</subject><subject>Lysine</subject><subject>mechanical exfoliation</subject><subject>Mechanical properties</subject><subject>Physical properties</subject><subject>Polymers</subject><subject>Reagents</subject><subject>Self healing 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Binyuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of Boron Nitride Nanoplatelets via Amino Acid Assisted Ball Milling: Towards Thermal Conductivity Application</atitle><jtitle>Nanomaterials (Basel, Switzerland)</jtitle><date>2020-08-22</date><risdate>2020</risdate><volume>10</volume><issue>9</issue><spage>1652</spage><pages>1652-</pages><issn>2079-4991</issn><eissn>2079-4991</eissn><abstract>Hexagonal boron nitride nanoplatelets (BNNPs) have attracted widespread attention due to their unique physical properties and their peeling from the base material. 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Meanwhile, the mechanical and self-healing properties of the composites were simultaneously largely enhanced.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>32842698</pmid><doi>10.3390/nano10091652</doi><orcidid>https://orcid.org/0000-0002-8204-4845</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Amino acids Aqueous solutions Ball milling Boron Boron nitride Carbon Carboxyl group Communication Composite materials Ethanol Experiments Fillers Fourier transforms Glutamic acid Graphene Heat conductivity Heat transfer hexagonal boron nitride nanoplatelets Hydrogels Lysine mechanical exfoliation Mechanical properties Physical properties Polymers Reagents Self healing materials self-healing Spectrum analysis Thermal conductivity |
| title | Preparation of Boron Nitride Nanoplatelets via Amino Acid Assisted Ball Milling: Towards Thermal Conductivity Application |
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