Internal Conversion vs. Intersystem Crossing – What Drives the Dynamics of Cyclic α,β-Enones?

The origin of ultrafast intersystem crossing and its competitiveness with singlet pathways was studied in cyclic alpha , beta -enones by transient absorption, time-resolved photoelectron spectroscopy and ab initio calculations.

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Bibliographic Details
Published in:EPJ Web of conferences 2013-01, Vol.41, p.5029-np
Main Authors: Schalk, O., Lang, P., Schuurman, M. S., Wu, G., Bradler, M., Riedle, E., Stolow, A.
Format: Article
Language:English
Subjects:
Dynamics
Internal conversion
Mathematical analysis
Origins
Pathways
Photoelectron spectroscopy
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Description
Summary:The origin of ultrafast intersystem crossing and its competitiveness with singlet pathways was studied in cyclic alpha , beta -enones by transient absorption, time-resolved photoelectron spectroscopy and ab initio calculations.
ISSN:2100-014X
2100-014X
DOI:10.1051/epjconf/20134105029