Hexakis(dimethylformamide-κ O )manganese(II) (dimethylformamide-κ O )pentakis(thiocyanato-κ N )chromate(III)

The title compound, [Mn(C 3 H 7 NO) 6 ][Cr(NCS) 5 (C 3 H 7 NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hydroxyethyl)tetrazole as starting materials. The crystal structur...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-06, Vol.68 (6), p.m823-m823
Main Authors: Semenaka, Valentyna V., Nesterova, Oksana V., Kokozay, Vladimir N., Omelchenko, Irina V., Shishkin, Oleg V.
Format: Article
Language:English
Online Access:Get full text
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Summary:The title compound, [Mn(C 3 H 7 NO) 6 ][Cr(NCS) 5 (C 3 H 7 NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hydroxyethyl)tetrazole as starting materials. The crystal structure of the complex consists of an [Mn(dmf) 6 ] 2+ cation and a [Cr(NCS) 5 (dmf)] 2− anion (dmf = dimethylformamide). The Mn II and Cr III atoms show a slightly distorted octahedral MnO 6 and CrN 5 O coordination geometries with adjacent angles in the range 85.29 (13)–95.96 (14)°.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812023069