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Fumed-Si-Pr-Pi a new Ag+ ion chemosensor in aqueous media

The surface of fumed silica nanoparticles can react with various organic groups. Fumed-silica can be functionalized by the reaction of (3-Chloropropyl)trimethoxysilane (CPTMS) to yield Fumed-Si-Pr-Cl, followed by the treatment with piperazine to obtain Fumed-Si-Pr-Pi, which was applied to detect met...

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Bibliographic Details
Published in:Results in Chemistry 2023-12, Vol.6, p.101156, Article 101156
Main Authors: Saberi Afshar, Sepideh, Mohammadi Ziarani, Ghodsi, Mohajer, Fatemeh, Badiei, Alireza
Format: Article
Language:English
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Summary:The surface of fumed silica nanoparticles can react with various organic groups. Fumed-silica can be functionalized by the reaction of (3-Chloropropyl)trimethoxysilane (CPTMS) to yield Fumed-Si-Pr-Cl, followed by the treatment with piperazine to obtain Fumed-Si-Pr-Pi, which was applied to detect metal ions. The optical activity of Fumed-Si-Pr-Pi was studied by fluorescence spectroscopy. It was demonstrated that among all different cations, the Ag+ ions quenched the PL of the Fumed-Si-Pr-Pi more strongly than other heavy metals, with LOD 5.43 × 10−7 M.
ISSN:2211-7156
2211-7156
DOI:10.1016/j.rechem.2023.101156