Bis[4-amino- N -(pyrimidin-2-yl-κ N )benzenesulfonamidato-κ N ](4,4′-dimethyl-2,2′-bipyridine-κ 2 N , N ′)cadmium dimethylformamide disolvate

In the title compound, [Cd(C10H9N4O2S)2(C12H12N2)]·2C3H7NO, the CdII ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-03, Vol.68 (3), p.m276-m277
Main Authors: Hossain, G. M. Golzar, Amoroso, A. J.
Format: Article
Language:English
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Summary:In the title compound, [Cd(C10H9N4O2S)2(C12H12N2)]·2C3H7NO, the CdII ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethylformamide molecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetrahedral. The crystal structure involves N—H...O hydrogen bonds which link molecules into a three-dimensional network. Weak C—H...O hydrogen bonds are also observed.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812004412