Ultrasound-Assisted Aqueous Extraction of Biocompounds from Orange Byproduct: Experimental Kinetics and Modeling

• Published in: Antioxidants 2020-04, Vol.9 (4), p.352
• Main Authors: Dalmau, Esperanza, Rosselló, Carmen, Eim, Valeria, Ratti, Cristina, Simal, Susana
• Format: Article
• Language: English
• Subjects: Acids; Acoustics; Albedo; antioxidant compounds; Antioxidants; Chemical properties; Composition; Coumaric acid; Extraction (Chemistry); Ferulic acid; Flavonoids; Food; Hesperidin; Identification and classification; Lipophilic; Materia medica, Vegetable; Mathematical models; Methods; Orange; orange byproduct; Phenolic compounds; Plant extracts; Raw materials; Sinapic acid; Solvents; Ultrasonic imaging; Ultrasound; ultrasound-assisted extraction; Weibull model
• ISSN: 2076-3921; 2076-3921
• DOI: 10.3390/antiox9040352

Orange byproduct (flavedo and albedo) from juice extraction, was used as raw material for this study. Kinetics of total phenolic and total flavonoid contents and antioxidant activity was experimentally determined during both conventional (agitation at 80 rpm) and ultrasound assisted (at 520 and 790 W/L) aqueous extraction from orange byproduct at 5, 15, and 25 °C. An extraction mathematical model was also developed. Significant increase of biocompounds extraction yields was observed as temperature and acoustic power density increased. Ultrasound assistance allowed higher yields at lower temperatures and shorter times. Yields of total phenolic and total flavonoid contents and antioxidant activity obtained with ultrasound extraction (790 W/L, 25 °C, 3 min) were 29%, 39%, and 197% higher, respectively, than those obtained by conventional extraction. The extraction kinetics curves were properly represented by the Weibull model for both conventional and acoustic extraction (mean relative error lower than 5%). Naringin, neohesperidin, and hesperidin were the main phenolic compounds found in the extracts, followed by ferulic, sinapic, and cuomaric acids. Neohesperidin, hesperidin, coumaric acid, and sinapic acid presented the highest yields, especially when extraction was assisted by ultrasound. Meanwhile, naringin and ferulic acid were extracted in a lesser extent, most likely due to their lipophilic character.