Self-Cleaning and Antibacterial Properties of the Cement Mortar with ZnO/Hydroxyapatite Powders

• Published in: Inorganics 2022-12, Vol.10 (12), p.241
• Main Authors: Mocioiu, Ana-Maria, Mohanu, Ileana, Piticescu, Roxana Mioara, Tudor, Ioan Albert, Petre, Ionela, Ghiță, Mihai, Ghiță, Andreea Nicoleta, Ioța, Miruna Adriana, Vitan, Nicoleta, Enache, Mădălin, Neagu, Simona
• Format: Article
• Language: English
• Subjects: Adsorption; Analysis; Antibacterial activity; antibacterial properties; Cement; cement mortar; Cleaning; Decoloring; Diffraction; E coli; Gram-negative bacteria; Gram-positive bacteria; Hydration; hydrothermal; Hydroxyapatite; Methylene blue; Mortar; Mortars (material); Nanoparticles; Photocatalysis; Polyethylene glycol; Properties; Radiation; Raw materials; Rhodamine; Scanning electron microscopy; Scanning microscopy; self-cleaning; Sensors; Software; Spectroscopy; Spectrum analysis; Structure; Ultraviolet radiation; X-ray diffraction; X-rays; Zinc oxide; Zinc oxides; ZnO/Hap
• ISSN: 2304-6740; 2304-6740
• DOI: 10.3390/inorganics10120241

According to literature data, different micro- and nanopowders have been used as a partial substitute for cement mortar due to their small size and large specific surface area. The aim of the work is to develop innovative materials based on cement mortar with antibacterial and self-cleaning properties, which can be used in the long-term maintenance of clean spaces. First, zinc oxide/hydroxyapatite (ZnO/Hap) powder denoted as ZH was synthesized by the hydrothermal method; then it was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM)/ energy dispersive spectroscopy (EDS), and adsorption–desorption isotherms. The second step was the cement mortar preparation: one plain, denoted E, and one with ZH powder inside, denoted MZH. Both mortars were subjected to self-cleaning and antibacterial tests. In the self-cleaning tests, two concentrated solutions of rhodamine B and methylene blue were used. MZH showed a better decolorating after 24 h of UV light than plain cement mortar denoted E for both solutions. In order to highlight the antibacterial effect of cement mortars on some strains of Gram-positive and Gram-negative bacteria, the direct contact method was used. The study revealed that, after 24 h of incubation, the planktonic growth of the E. coli strain is significantly inhibited in the presence of the MZH sample, compared to the control strain. MZH cement mortar exhibits a better growth inhibitory property than the plain cement mortar E.