Conversion of Biomass-Derived Molecules into Alkyl Levulinates Using Heterogeneous Catalysts

• Published in: Reactions (Basel, Switzerland) Switzerland), 2023-12, Vol.4 (4), p.667-678
• Main Authors: Yamanaka, Nobutaka, Shimazu, Shogo
• Format: Article
• Language: English
• Subjects: Alcohol; alkyl levulinates; Biodiesel fuels; Biomass; biomass-derived molecules; Carbon; Catalysts; Cellulose; Chemical synthesis; Esterification; Fuel additives; Furfural; Furfuryl alcohol; Glucose; Levulinic acid; Lignin; Reagents; Synergistic effect
• ISSN: 2624-781X; 2624-781X
• DOI: 10.3390/reactions4040038

Alkyl levulinates are promising and versatile biomass-derived chemicals, which are utilized as fuel additives, flavoring agents, fragrances, solvents, and precursors for synthesizing valuable γ-valerolactone. A method for synthesizing alkyl levulinates involves the esterification of levulinic acid with the corresponding alkyl alcohols in the presence of solid acid catalysts that have abundant Brønsted acid sites. Alkyl levulinates can also be synthesized from other biomass-derived molecules such as furfuryl alcohol and furfural via alcoholysis and one-pot conversion, respectively. Thus far, various heterogeneous catalysts have been developed for the conversion of the biomass-derived molecules (levulinic acid, furfuryl alcohol, and furfural) into alkyl levulinates. To obtain the target products in high yields, numerous strategies have been employed including increasing Brønsted acidity, dispersing and incorporating Brønsted acid sites, inducing the formation of mesopores, and inducing a synergistic effect of metal–Brønsted acid sites that are present on a catalyst surface. Here, we summarily reviewed the performances of the heterogeneous catalysts in the conversions, describing the design and development of the heterogeneous catalysts that ensured the excellent yield of alkyl levulinates.