Photophysics and photochemistry of NIR absorbers derived from cyanines: key to new technologies based on chemistry 4.0

• Published in: Beilstein journal of organic chemistry 2020-03, Vol.16 (1), p.415-444
• Main Authors: Strehmel, Bernd, Schmitz, Christian, Kütahya, Ceren, Pang, Yulian, Drewitz, Anke, Mustroph, Heinz
• Format: Article
• Language: English
• Subjects: Chemistry; chemistry 4.0; cyanine; Evaporation; Hydrophobicity; Lasers; Light sources; near infrared; Photography; photopolymer; polymer synthesis; Review; sensitizer
• ISSN: 1860-5397; 2195-951X; 1860-5397
• DOI: 10.3762/bjoc.16.40

Cyanines derived from heptamethines were mainly discussed regarding their functionalization to broaden the solubility in different surroundings exhibiting either hydrophilic or hydrophobic properties and to tailor made the Δ photopysical properties with respect to absorption and fluorescence. Electrochemical properties were additionally considered for some selected examples. The cyanines chosen comprised as end groups either indolenine, benzo[ ]- or benzo[ ]indolium pattern, which facilitated to shift the absorption between 750-1000 nm. This enabled their use in applications with light sources emitting in the near-infrared (NIR) region selected from high power LEDs or lasers with line-shaped focus. The absorbers considered were discussed regarding their function as sensitizer for applications related to Chemistry 4.0 standards. These were mainly photopolymer coatings, which can be found for applications in the graphic industry or to protect selected substrates. The huge release of heat on demand upon turning ON or OFF the NIR light source enables them for photothermal treatment in processes requesting heat to initiate either chemical (activated reactions) or physical (melting, evaporation) events.