2-[(E)-(1,10-Phenanthrolin-5-yl)imino-meth-yl]phenol methanol monosolvate

In the title multi-donor Schiff base compound, C(19)H(13)N(3)O·CH(3)OH, the dihedral angle between the mean planes of the phenanthroline and phenol rings is 59.3 (1)°. The Schiff base mol-ecule is linked to the solvent mol-ecule by an O-H⋯O hydrogen bond. In the crystal, the components are linked by...

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Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-04, Vol.68 (Pt 4), p.o1173-o1174
Main Authors: Oztürk Yíldírím, Sema, Demirhan, Nebahat, Elmalí, Fikriye, Butcher, Ray J
Format: Article
Language:English
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Organic Papers
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Summary:In the title multi-donor Schiff base compound, C(19)H(13)N(3)O·CH(3)OH, the dihedral angle between the mean planes of the phenanthroline and phenol rings is 59.3 (1)°. The Schiff base mol-ecule is linked to the solvent mol-ecule by an O-H⋯O hydrogen bond. In the crystal, the components are linked by O-H⋯N hydrogen bonds, weak O-H⋯N inter-actions and π-π stacking inter-actions [centroid-centroid distances = 3.701 (1) and 3.656 (1) Å].
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812011890