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Highly Reversible Zn Anodes through a Hydrophobic Interface Formed by Electrolyte Additive
Hydrogen evolution reaction and dendrite growth seriously break the Zn plating/stripping process at the electrolyte/electrode interface, causing the instability of the Zn anode of aqueous zinc ion batteries. To improve the Zn anode stability and reversibility, we report a new electrolyte additive of...
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| Published in: | Nanomaterials (Basel, Switzerland) Switzerland), 2023-05, Vol.13 (9), p.1547 |
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| Main Authors: | , , , , , , |
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| cited_by | cdi_FETCH-LOGICAL-c518t-a554684412c78e56b1fa1111c0d07bd6f0edb1e1a492291bfab5e423ce035003 |
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| cites | cdi_FETCH-LOGICAL-c518t-a554684412c78e56b1fa1111c0d07bd6f0edb1e1a492291bfab5e423ce035003 |
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| container_issue | 9 |
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| container_title | Nanomaterials (Basel, Switzerland) |
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| creator | Yan, Xiaoying Tong, Yunwei Liu, Yingjie Li, Xinyu Qin, Zhenbo Wu, Zhong Hu, Wenbin |
| description | Hydrogen evolution reaction and dendrite growth seriously break the Zn plating/stripping process at the electrolyte/electrode interface, causing the instability of the Zn anode of aqueous zinc ion batteries. To improve the Zn anode stability and reversibility, we report a new electrolyte additive of aqueous electrolyte with the hydrophobic group. This interfacial hydrophobicity maximises the exclusion of free water from the Zn anode surface, which blocks water erosion and reduces interfacial side reactions. Thus, in an optimal 2 M ZnSO
electrolyte with 2 g·L
Tween-85, the hydrogen evolution reaction and other water-induced undesired reactions can be suppressed, which greatly improves the cycling stability and Coulombic efficiency (CE) of Zn plating/stripping process. The stable cycle time of the Zn//Zn symmetric battery reaches over 1300 h, especially at a high current density and a high areal capacity (more than 650 h at 5 mA·cm
, 5 mAh·cm
). The average Coulomb efficiency (CE) of Zn//Ti asymmetric cell achieves 98.11% after 300 cycles. The capacity retention rate of Zn//MnO
full battery is up to 88.6% after 1000 cycles. |
| doi_str_mv | 10.3390/nano13091547 |
| format | article |
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electrolyte with 2 g·L
Tween-85, the hydrogen evolution reaction and other water-induced undesired reactions can be suppressed, which greatly improves the cycling stability and Coulombic efficiency (CE) of Zn plating/stripping process. The stable cycle time of the Zn//Zn symmetric battery reaches over 1300 h, especially at a high current density and a high areal capacity (more than 650 h at 5 mA·cm
, 5 mAh·cm
). The average Coulomb efficiency (CE) of Zn//Ti asymmetric cell achieves 98.11% after 300 cycles. The capacity retention rate of Zn//MnO
full battery is up to 88.6% after 1000 cycles.</description><identifier>ISSN: 2079-4991</identifier><identifier>EISSN: 2079-4991</identifier><identifier>DOI: 10.3390/nano13091547</identifier><identifier>PMID: 37177092</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Alternative energy sources ; Analysis ; Anodes ; Aqueous electrolytes ; Cell cycle ; Chemical reactions ; Contact angle ; Cycle time ; Electric properties ; Electrodes ; electrolyte additive ; Electrolytes ; Energy resources ; Energy storage ; HER ; Hydrogen evolution reactions ; Hydrophobicity ; Interface stability ; Lithium ; Manganese dioxide ; Mechanical properties ; Methods ; Plating ; Rechargeable batteries ; Side reactions ; Water erosion ; Zinc ; Zinc sulfate ; Zinc-ion batteries</subject><ispartof>Nanomaterials (Basel, Switzerland), 2023-05, Vol.13 (9), p.1547</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2023 by the authors. 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c518t-a554684412c78e56b1fa1111c0d07bd6f0edb1e1a492291bfab5e423ce035003</citedby><cites>FETCH-LOGICAL-c518t-a554684412c78e56b1fa1111c0d07bd6f0edb1e1a492291bfab5e423ce035003</cites><orcidid>0000-0002-5943-065X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2812509313/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2812509313?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37177092$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yan, Xiaoying</creatorcontrib><creatorcontrib>Tong, Yunwei</creatorcontrib><creatorcontrib>Liu, Yingjie</creatorcontrib><creatorcontrib>Li, Xinyu</creatorcontrib><creatorcontrib>Qin, Zhenbo</creatorcontrib><creatorcontrib>Wu, Zhong</creatorcontrib><creatorcontrib>Hu, Wenbin</creatorcontrib><title>Highly Reversible Zn Anodes through a Hydrophobic Interface Formed by Electrolyte Additive</title><title>Nanomaterials (Basel, Switzerland)</title><addtitle>Nanomaterials (Basel)</addtitle><description>Hydrogen evolution reaction and dendrite growth seriously break the Zn plating/stripping process at the electrolyte/electrode interface, causing the instability of the Zn anode of aqueous zinc ion batteries. To improve the Zn anode stability and reversibility, we report a new electrolyte additive of aqueous electrolyte with the hydrophobic group. This interfacial hydrophobicity maximises the exclusion of free water from the Zn anode surface, which blocks water erosion and reduces interfacial side reactions. Thus, in an optimal 2 M ZnSO
electrolyte with 2 g·L
Tween-85, the hydrogen evolution reaction and other water-induced undesired reactions can be suppressed, which greatly improves the cycling stability and Coulombic efficiency (CE) of Zn plating/stripping process. The stable cycle time of the Zn//Zn symmetric battery reaches over 1300 h, especially at a high current density and a high areal capacity (more than 650 h at 5 mA·cm
, 5 mAh·cm
). The average Coulomb efficiency (CE) of Zn//Ti asymmetric cell achieves 98.11% after 300 cycles. The capacity retention rate of Zn//MnO
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Wenbin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Reversible Zn Anodes through a Hydrophobic Interface Formed by Electrolyte Additive</atitle><jtitle>Nanomaterials (Basel, Switzerland)</jtitle><addtitle>Nanomaterials (Basel)</addtitle><date>2023-05-05</date><risdate>2023</risdate><volume>13</volume><issue>9</issue><spage>1547</spage><pages>1547-</pages><issn>2079-4991</issn><eissn>2079-4991</eissn><abstract>Hydrogen evolution reaction and dendrite growth seriously break the Zn plating/stripping process at the electrolyte/electrode interface, causing the instability of the Zn anode of aqueous zinc ion batteries. To improve the Zn anode stability and reversibility, we report a new electrolyte additive of aqueous electrolyte with the hydrophobic group. This interfacial hydrophobicity maximises the exclusion of free water from the Zn anode surface, which blocks water erosion and reduces interfacial side reactions. Thus, in an optimal 2 M ZnSO
electrolyte with 2 g·L
Tween-85, the hydrogen evolution reaction and other water-induced undesired reactions can be suppressed, which greatly improves the cycling stability and Coulombic efficiency (CE) of Zn plating/stripping process. The stable cycle time of the Zn//Zn symmetric battery reaches over 1300 h, especially at a high current density and a high areal capacity (more than 650 h at 5 mA·cm
, 5 mAh·cm
). The average Coulomb efficiency (CE) of Zn//Ti asymmetric cell achieves 98.11% after 300 cycles. The capacity retention rate of Zn//MnO
full battery is up to 88.6% after 1000 cycles.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>37177092</pmid><doi>10.3390/nano13091547</doi><orcidid>https://orcid.org/0000-0002-5943-065X</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Publicly Available Content Database; PubMed Central |
| subjects | Alternative energy sources Analysis Anodes Aqueous electrolytes Cell cycle Chemical reactions Contact angle Cycle time Electric properties Electrodes electrolyte additive Electrolytes Energy resources Energy storage HER Hydrogen evolution reactions Hydrophobicity Interface stability Lithium Manganese dioxide Mechanical properties Methods Plating Rechargeable batteries Side reactions Water erosion Zinc Zinc sulfate Zinc-ion batteries |
| title | Highly Reversible Zn Anodes through a Hydrophobic Interface Formed by Electrolyte Additive |
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