Platinum Complexes from C-H Activation of Sterically Hindered [C^N] Donor Benzothiophene Imine Ligands: Synthesis and Photophysical Properties

Primary amines and benzothiophene-3-carboxaldehyde were reacted to give four large, bulky imine ligands. These imine ligands were reacted with a tetramethyl platinum dimer and by heteroatom-assisted C-H activation, both monometalated compounds and bismetalated compounds were synthesized. In all case...

Full description

Saved in:
Bibliographic Details
Published in:ACS omega 2020-10, Vol.5 (41), p.26855-26863
Main Authors: Anderson, Craig M, Coffey, Belle, Morales, Leslie, Greenberg, Matthew W, Norman, Matthew, Weinstein, Michael, Brown, Garrett, Tanski, Joseph M
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Primary amines and benzothiophene-3-carboxaldehyde were reacted to give four large, bulky imine ligands. These imine ligands were reacted with a tetramethyl platinum dimer and by heteroatom-assisted C-H activation, both monometalated compounds and bismetalated compounds were synthesized. In all cases, five-membered platinacycles were formed. The compounds were characterized by NMR spectroscopy, and one bismetalated compound was characterized by single-crystal X-ray diffraction. The UV-vis absorption and emission spectra and the excited-state lifetimes were recorded for these complexes. Density functional theory (DFT) and time-dependent-DFT calculations were performed to aid in the assignment of the absorption and emission spectra of the newly synthesized complexes.
ISSN:2470-1343
2470-1343
DOI:10.1021/acsomega.0c03993