Conductive Metal–Organic Frameworks for Rechargeable Lithium Batteries

Currently, rechargeable lithium batteries are representative of high-energy-density battery systems. Nevertheless, the development of rechargeable lithium batteries is confined by numerous problems, such as anode volume expansion, dendrite growth of lithium metal, separator interface compatibility,...

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Bibliographic Details
Published in:Batteries (Basel) 2023-02, Vol.9 (2), p.109
Main Authors: Deng, Fengjun, Zhang, Yuhang, Yu, Yingjian
Format: Article
Language:English
Subjects:
Air batteries
Analysis
Batteries
Charge transport
conductive metal–organic frameworks
Design and construction
Electrochemical reactions
Electrochemistry
Energy storage
Heat resistance
Insulation
Interface stability
Ligands
Lithium
Lithium batteries
Lithium cells
Lithium sulfur batteries
Lithium-ion batteries
Li–air batteries
Li–S batteries
Materials
Metal-organic frameworks
Organometallic compounds
Performance degradation
Rechargeable batteries
Semiconductors
Transport properties
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Summary:Currently, rechargeable lithium batteries are representative of high-energy-density battery systems. Nevertheless, the development of rechargeable lithium batteries is confined by numerous problems, such as anode volume expansion, dendrite growth of lithium metal, separator interface compatibility, and instability of cathode interface, leading to capacity fade and performance degradation of batteries. Since the 21st century, metal–organic frameworks (MOFs) have attracted much attention in energy-related applications owing to their ideal specific surface areas, adjustable pore structures, and targeted design functions. The insulating characteristics of traditional MOFs restrict their application in the field of electrochemistry energy storage. Recently, some teams have broken this bottleneck through the design and synthesis of electron- and proton-conductive MOFs (c-MOFs), indicating excellent charge transport properties, while the chemical and structural advantages of MOFs are still maintained. In this review, we profile the utilization of c-MOFs in several rechargeable lithium batteries such as lithium-ion batteries, Li–S batteries, and Li–air batteries. The preparation methods, conductive mechanisms, experimental and theoretical research of c-MOFs are systematically elucidated and summarized. Finally, in the field of electrochemical energy storage and conversion, challenges and opportunities can coexist.
ISSN:2313-0105
2313-0105
DOI:10.3390/batteries9020109