Glycosylated Metal Phthalocyanines

In the first part; the syntheses of mono-; di-; and tetra-glycosylated phthalonitriles is described; which are the most used starting materials for the preparation of the corresponding glycosylated metal (mostly zinc) phthalocyanines. In the second section; the preparation of symmetric and unsymmetr...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2015-11, Vol.20 (11), p.20173-20185
Main Author: Hanack, Michael
Format: Article
Language:English
Subjects:
Chlorophyll
Chromatography
Glycosylation
Hemoglobin
Humans
Indoles - chemical synthesis
Indoles - chemistry
Ligands
Metals
Metals - chemistry
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
phthalocyanines
phthalonitriles
Zinc
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Summary:In the first part; the syntheses of mono-; di-; and tetra-glycosylated phthalonitriles is described; which are the most used starting materials for the preparation of the corresponding glycosylated metal (mostly zinc) phthalocyanines. In the second section; the preparation of symmetric and unsymmetric mono-; tetra-; and octa- glycosylated zinc phthalocyanines are reviewed; in which the sugar is attached to the phthalocyanine macrocycle; either anomerically or via another one of its OH-groups.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules201119683