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Crystal structure of tetrakis(μ-caproato-κ 2 O : O ′)bis[(4-cyanopyridine-κ N 1 )copper(II)]
The title dinuclear complex, [Cu 2 (C 6 H 11 O 2 ) 4 (C 6 H 4 N 2 ) 2 ], has a paddle-wheel structure. The two crystallographically independent Cu II atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the...
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| Published in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-11, Vol.71 (11), p.m195-m196 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c354t-8870513031d6ebaa174e304afadbcedb7a95137def2dd90d3c6edc82972a3dc43 |
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| cites | cdi_FETCH-LOGICAL-c354t-8870513031d6ebaa174e304afadbcedb7a95137def2dd90d3c6edc82972a3dc43 |
| container_end_page | m196 |
| container_issue | 11 |
| container_start_page | m195 |
| container_title | Acta crystallographica. Section E, Crystallographic communications |
| container_volume | 71 |
| creator | Baruah, Sukanya Islam, Zinnatara Karmakar, Sanjib Das, Birinchi Kumar |
| description | The title dinuclear complex, [Cu
2
(C
6
H
11
O
2
)
4
(C
6
H
4
N
2
)
2
], has a paddle-wheel structure. The two crystallographically independent Cu
II
atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyanopyridine ligand occupies the apical position. The Cu...Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H...N hydrogen bonds connect the molecules into chains along [11-1] and C—H...O hydrogen bonds link the chains into a three-dimensional network. |
| doi_str_mv | 10.1107/S2056989015019052 |
| format | article |
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2
(C
6
H
11
O
2
)
4
(C
6
H
4
N
2
)
2
], has a paddle-wheel structure. The two crystallographically independent Cu
II
atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyanopyridine ligand occupies the apical position. The Cu...Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H...N hydrogen bonds connect the molecules into chains along [11-1] and C—H...O hydrogen bonds link the chains into a three-dimensional network.</description><identifier>ISSN: 2056-9890</identifier><identifier>EISSN: 2056-9890</identifier><identifier>DOI: 10.1107/S2056989015019052</identifier><language>eng</language><publisher>International Union of Crystallography</publisher><subject>4-cyanopyridine ; crystal structure ; dicopper complex ; hexanoic acid</subject><ispartof>Acta crystallographica. Section E, Crystallographic communications, 2015-11, Vol.71 (11), p.m195-m196</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c354t-8870513031d6ebaa174e304afadbcedb7a95137def2dd90d3c6edc82972a3dc43</citedby><cites>FETCH-LOGICAL-c354t-8870513031d6ebaa174e304afadbcedb7a95137def2dd90d3c6edc82972a3dc43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Baruah, Sukanya</creatorcontrib><creatorcontrib>Islam, Zinnatara</creatorcontrib><creatorcontrib>Karmakar, Sanjib</creatorcontrib><creatorcontrib>Das, Birinchi Kumar</creatorcontrib><title>Crystal structure of tetrakis(μ-caproato-κ 2 O : O ′)bis[(4-cyanopyridine-κ N 1 )copper(II)]</title><title>Acta crystallographica. Section E, Crystallographic communications</title><description>The title dinuclear complex, [Cu
2
(C
6
H
11
O
2
)
4
(C
6
H
4
N
2
)
2
], has a paddle-wheel structure. The two crystallographically independent Cu
II
atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyanopyridine ligand occupies the apical position. The Cu...Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H...N hydrogen bonds connect the molecules into chains along [11-1] and C—H...O hydrogen bonds link the chains into a three-dimensional network.</description><subject>4-cyanopyridine</subject><subject>crystal structure</subject><subject>dicopper complex</subject><subject>hexanoic acid</subject><issn>2056-9890</issn><issn>2056-9890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNplkMtKw0AUhoMoWGofwF2W7SJ6ZiYz6biT4iVQ7EJdiYSTuUhq7YSZdJGdz-RSfIY-hE9iYkUEF4dz-P7Dt_ij6JjACSGQnd5S4EJOJRAORAKne9GgR0nP9v_ch9EohCUAkJQzwekgwplvQ4OrODR-o5qNN7GzcWMaj89VGG8_EoW1d9i4ZPse03gRn3Xz-fo2KavwME4T1eLa1a2vdLU2_c9NTOKJcnVt_DjPJ49H0YHFVTCjnz2M7i8v7mbXyXxxlc_O54liPG2S6TQDThgwooUpEUmWGgYpWtSlMrrMUHZxpo2lWkvQTAmj1ZTKjCLTKmXDKN95tcNlUfvqBX1bOKyKb-D8U4G-qdTKFAhWlGhl5-6KMBxtJgQFgSC5AFZ2LrJzKe9C8Mb--ggUfeXFv8rZF9XCdUM</recordid><startdate>20151101</startdate><enddate>20151101</enddate><creator>Baruah, Sukanya</creator><creator>Islam, Zinnatara</creator><creator>Karmakar, Sanjib</creator><creator>Das, Birinchi Kumar</creator><general>International Union of Crystallography</general><scope>AAYXX</scope><scope>CITATION</scope><scope>DOA</scope></search><sort><creationdate>20151101</creationdate><title>Crystal structure of tetrakis(μ-caproato-κ 2 O : O ′)bis[(4-cyanopyridine-κ N 1 )copper(II)]</title><author>Baruah, Sukanya ; Islam, Zinnatara ; Karmakar, Sanjib ; Das, Birinchi Kumar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c354t-8870513031d6ebaa174e304afadbcedb7a95137def2dd90d3c6edc82972a3dc43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>4-cyanopyridine</topic><topic>crystal structure</topic><topic>dicopper complex</topic><topic>hexanoic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baruah, Sukanya</creatorcontrib><creatorcontrib>Islam, Zinnatara</creatorcontrib><creatorcontrib>Karmakar, Sanjib</creatorcontrib><creatorcontrib>Das, Birinchi Kumar</creatorcontrib><collection>CrossRef</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baruah, Sukanya</au><au>Islam, Zinnatara</au><au>Karmakar, Sanjib</au><au>Das, Birinchi Kumar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of tetrakis(μ-caproato-κ 2 O : O ′)bis[(4-cyanopyridine-κ N 1 )copper(II)]</atitle><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle><date>2015-11-01</date><risdate>2015</risdate><volume>71</volume><issue>11</issue><spage>m195</spage><epage>m196</epage><pages>m195-m196</pages><issn>2056-9890</issn><eissn>2056-9890</eissn><abstract>The title dinuclear complex, [Cu
2
(C
6
H
11
O
2
)
4
(C
6
H
4
N
2
)
2
], has a paddle-wheel structure. The two crystallographically independent Cu
II
atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyanopyridine ligand occupies the apical position. The Cu...Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H...N hydrogen bonds connect the molecules into chains along [11-1] and C—H...O hydrogen bonds link the chains into a three-dimensional network.</abstract><pub>International Union of Crystallography</pub><doi>10.1107/S2056989015019052</doi><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2056-9890 |
| ispartof | Acta crystallographica. Section E, Crystallographic communications, 2015-11, Vol.71 (11), p.m195-m196 |
| issn | 2056-9890 2056-9890 |
| language | eng |
| recordid | cdi_doaj_primary_oai_doaj_org_article_a0f6baf9fad145e5af766206a095603b |
| source | IngentaConnect Journals; PubMed Central |
| subjects | 4-cyanopyridine crystal structure dicopper complex hexanoic acid |
| title | Crystal structure of tetrakis(μ-caproato-κ 2 O : O ′)bis[(4-cyanopyridine-κ N 1 )copper(II)] |
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