Electrical and Thermal Conductivities of Single CuxO Nanowires

• Published in: Nanomaterials (Basel, Switzerland) Switzerland), 2023-11, Vol.13 (21), p.2822
• Main Authors: De Carlo, Ivan, Baudino, Luisa, Klapetek, Petr, Serrapede, Mara, Michieletti, Fabio, De Leo, Natascia, Pirri, Fabrizio, Boarino, Luca, Lamberti, Andrea, Milano, Gianluca
• Format: Article
• Language: English
• Subjects: Chemical composition; Conductivity; Copper; Copper oxides; CuO; Electric contacts; Electrical properties; Electrodes; Electronics; Electrons; Energy storage; Environmental impact; Finite difference method; Gas sensors; Heat conductivity; Heat transfer; High aspect ratio; Investigations; Metal foils; Microscopy; Nanotechnology; Nanowires; Optoelectronic devices; Oxidation; Scanning thermal microscopy; Sensors; single-nanowire electrical characterization; Software; Spectrum analysis; SThM on single nanowire; Structural analysis; Substrates; Thermal conductivity; Thermal properties; Thermodynamic properties; VOCs; Volatile organic compounds
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano13212822

Copper oxide nanowires (NWs) are promising elements for the realization of a wide range of devices for low-power electronics, gas sensors, and energy storage applications, due to their high aspect ratio, low environmental impact, and cost-effective manufacturing. Here, we report on the electrical and thermal properties of copper oxide NWs synthetized through thermal growth directly on copper foil. Structural characterization revealed that the growth process resulted in the formation of vertically aligned NWs on the Cu growth substrate, while the investigation of chemical composition revealed that the NWs were composed of CuO rather than Cu2O. The electrical characterization of single-NW-based devices, in which single NWs were contacted by Cu electrodes, revealed that the NWs were characterized by a conductivity of 7.6 × 10−2 S∙cm−1. The effect of the metal–insulator interface at the NW–electrode contact was analyzed by comparing characterizations in two-terminal and four-terminal configurations. The effective thermal conductivity of single CuO NWs placed on a substrate was measured using Scanning Thermal Microscopy (SThM), providing a value of 2.6 W∙m−1∙K−1, and using a simple Finite Difference model, an estimate for the thermal conductivity of the nanowire itself was obtained as 3.1 W∙m−1∙K−1. By shedding new light on the electrical and thermal properties of single CuO NWs, these results can be exploited for the rational design of a wide range of optoelectronic devices based on NWs.