1,3-Bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium trichlorido(η 6 - p -cymene)ruthenate(II)

The asymmetric unit of the title compound, (C14H17N2S2)[Ru(C10H14)Cl3], contains a 1,3-bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium cation and a trichlorido(η6-p-cymene)ruthenate(II) anion. The Ru atom exhibits a distorted octahedral coordination with the benzene ring of the p-cymene liga...

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Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-01, Vol.65 (1), p.m111-m112
Main Authors: Arslan, Hakan, VanDerveer, Don, Özdemir, İsmail, Gürbüz, Nevin, Gök, Yetkin, Çetinkaya, Bekir
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container_title Acta crystallographica. Section E, Structure reports online
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creator Arslan, Hakan
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description The asymmetric unit of the title compound, (C14H17N2S2)[Ru(C10H14)Cl3], contains a 1,3-bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium cation and a trichlorido(η6-p-cymene)ruthenate(II) anion. The Ru atom exhibits a distorted octahedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three chloride atoms occupying the other three sites. The N-C bond lengths of the N-C-N unit of the pyrimidinium cation are shorter than the average single C-N bond length of 1.48 Å, thus showing double-bond character, indicating a partial electron delocalization within the N-C-N fragment. The pyrimidine ring has an envelope conformation. Four intermolecular C-H...Cl hydrogen bonds generate a three-dimensional hydrogen-bonded framework.
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title 1,3-Bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium trichlorido(η 6 - p -cymene)ruthenate(II)
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