4-(Di-methyl-amino)-pyridinium trichlorido[4-(di-methyl-amino)-pyridine-κN]cobaltate(II)

In the anion of the title compound, (C7H11N2)[CoCl3(C7H10N2)], the Co(II) ion is coordinated by one N atom from a 4-(di-methyl-amino)-pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl3 polyhedron with a distorted tetra-hedral geometry. In the crystal, cations and anions are linked via weak...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-07, Vol.69 (Pt 7), p.m379-m380
Main Authors: Guenifa, Fatiha, Hadjadj, Nasreddine, Zeghouan, Ouahida, Bendjeddou, Lamia, Merazig, Hocine
Format: Article
Language:English
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Metal-Organic Papers
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Summary:In the anion of the title compound, (C7H11N2)[CoCl3(C7H10N2)], the Co(II) ion is coordinated by one N atom from a 4-(di-methyl-amino)-pyridine (DMAP) ligand and three Cl atoms, forming a CoNCl3 polyhedron with a distorted tetra-hedral geometry. In the crystal, cations and anions are linked via weak N-H⋯Cl and C-H⋯Cl hydrogen bonds. Double layers of complex anions stack along the b- axis direction, which alternate with double layers of 4-(di-methyl-amino)-pyridinium cations.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813015602