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Photocatalytic Removal of Water Emerging Pollutants in an Optimized Packed Bed Photoreactor Using Solar Light
Photocatalysis is an advanced oxidation process that is an environmentally friendly option and one of the most critical technologies in green chemistry today. This work studied the upscaling of photocatalysis as a suitable process for wastewater treatment to remove emerging pollutants. For this purp...
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Published in: | Catalysts 2023-06, Vol.13 (6), p.1023 |
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description | Photocatalysis is an advanced oxidation process that is an environmentally friendly option and one of the most critical technologies in green chemistry today. This work studied the upscaling of photocatalysis as a suitable process for wastewater treatment to remove emerging pollutants. For this purpose, unsupported and supported TiO2 photocatalysts were tested in the photodegradation of ciprofloxacin as a model molecule of an emerging wastewater component, using visible, UV radiation, and solar light. The suitability of TiO2 as a photocatalyst to decompose ciprofloxacin was confirmed in batch photoreactor under Visible and UV radiation, with degradation rates up to 90% after 30 min of irradiation and low adsorption values. TiO2 as a photocatalyst coated in glass support material at the packed bed photoreactor showed good photoactivity for emergent contaminants degradation (95%) under solar radiation. It has been possible to verify that the photocatalytic reactor system constitutes a viable process for eliminating emerging contaminants through environmentally sustainable treatments. Our results corroborate the possibility of degrading emerging contaminants by solar radiation using a packed bed photoreactor, providing a more effective option from a practical and economical point of view for wastewater effluent treatments. |
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TiO2 as a photocatalyst coated in glass support material at the packed bed photoreactor showed good photoactivity for emergent contaminants degradation (95%) under solar radiation. It has been possible to verify that the photocatalytic reactor system constitutes a viable process for eliminating emerging contaminants through environmentally sustainable treatments. Our results corroborate the possibility of degrading emerging contaminants by solar radiation using a packed bed photoreactor, providing a more effective option from a practical and economical point of view for wastewater effluent treatments.</description><identifier>ISSN: 2073-4344</identifier><identifier>EISSN: 2073-4344</identifier><identifier>DOI: 10.3390/catal13061023</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Adsorption ; Catalysts ; Chemical reactions ; ciprofloxacin ; Climate change ; Contaminants ; Drinking water ; emerging contaminants ; endocrine-disrupting compounds ; Global temperature changes ; Laboratories ; Light ; Management ; Medical research ; Oxidation ; Packed beds ; packed-bed reactor ; Personal grooming ; Pharmaceuticals ; Photocatalysis ; Photocatalysts ; Photodegradation ; Pollutants ; Purification ; Radiation ; Sewage ; Solar radiation ; Titanium dioxide ; Ultraviolet radiation ; Veterinary medicine ; Wastewater ; Wastewater treatment ; Water ; Water pollution ; Water treatment</subject><ispartof>Catalysts, 2023-06, Vol.13 (6), p.1023</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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E.</creatorcontrib><creatorcontrib>de Paz Carmona, H.</creatorcontrib><creatorcontrib>Gutiérrez, M.</creatorcontrib><creatorcontrib>Esparza, P.</creatorcontrib><title>Photocatalytic Removal of Water Emerging Pollutants in an Optimized Packed Bed Photoreactor Using Solar Light</title><title>Catalysts</title><description>Photocatalysis is an advanced oxidation process that is an environmentally friendly option and one of the most critical technologies in green chemistry today. This work studied the upscaling of photocatalysis as a suitable process for wastewater treatment to remove emerging pollutants. For this purpose, unsupported and supported TiO2 photocatalysts were tested in the photodegradation of ciprofloxacin as a model molecule of an emerging wastewater component, using visible, UV radiation, and solar light. The suitability of TiO2 as a photocatalyst to decompose ciprofloxacin was confirmed in batch photoreactor under Visible and UV radiation, with degradation rates up to 90% after 30 min of irradiation and low adsorption values. TiO2 as a photocatalyst coated in glass support material at the packed bed photoreactor showed good photoactivity for emergent contaminants degradation (95%) under solar radiation. It has been possible to verify that the photocatalytic reactor system constitutes a viable process for eliminating emerging contaminants through environmentally sustainable treatments. Our results corroborate the possibility of degrading emerging contaminants by solar radiation using a packed bed photoreactor, providing a more effective option from a practical and economical point of view for wastewater effluent treatments.</description><subject>Adsorption</subject><subject>Catalysts</subject><subject>Chemical reactions</subject><subject>ciprofloxacin</subject><subject>Climate change</subject><subject>Contaminants</subject><subject>Drinking water</subject><subject>emerging contaminants</subject><subject>endocrine-disrupting compounds</subject><subject>Global temperature changes</subject><subject>Laboratories</subject><subject>Light</subject><subject>Management</subject><subject>Medical research</subject><subject>Oxidation</subject><subject>Packed beds</subject><subject>packed-bed reactor</subject><subject>Personal grooming</subject><subject>Pharmaceuticals</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Photodegradation</subject><subject>Pollutants</subject><subject>Purification</subject><subject>Radiation</subject><subject>Sewage</subject><subject>Solar radiation</subject><subject>Titanium dioxide</subject><subject>Ultraviolet radiation</subject><subject>Veterinary medicine</subject><subject>Wastewater</subject><subject>Wastewater treatment</subject><subject>Water</subject><subject>Water pollution</subject><subject>Water treatment</subject><issn>2073-4344</issn><issn>2073-4344</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNpVkd9r3DAMx8PoYKXr494Ne07r2Il_PHal6woHPbaVPRrFllPfkvjm-ArdXz-nN0ZngSWEvh9JqKo-NPSCc00vLWQYG05FQxl_U50yKnnd8rY9eRW_q86XZUfL0w1XTXdaTdvHmOOL-DkHS77iFJ9gJNGTH5AxkZsJ0xDmgWzjOB4yzHkhYSYwk_t9DlP4jY5swf4s7tMarriEYMtPHpZV-C2OkMgmDI_5ffXWw7jg-V9_Vj18vvl-_aXe3N_eXV9tattSnesee9ai7aHjjnEOzFkhet70rdSCguydp45J73rRdaApExKtlZRzr6SSlp9Vd0eui7Az-xQmSM8mQjAviZgGA6msO6IBJVCgKgDft4BO0045KZDz0s86KKyPR9Y-xV8HXLLZxUOay_iGKaalZl2jStXFsWqAAg2zjzmBLeZwCjbO6EPJX8mu1bJTbBXUR4FNcVkS-n9jNtSsFzX_XZT_AbcplQI</recordid><startdate>20230601</startdate><enddate>20230601</enddate><creator>Borges, M. 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subjects | Adsorption Catalysts Chemical reactions ciprofloxacin Climate change Contaminants Drinking water emerging contaminants endocrine-disrupting compounds Global temperature changes Laboratories Light Management Medical research Oxidation Packed beds packed-bed reactor Personal grooming Pharmaceuticals Photocatalysis Photocatalysts Photodegradation Pollutants Purification Radiation Sewage Solar radiation Titanium dioxide Ultraviolet radiation Veterinary medicine Wastewater Wastewater treatment Water Water pollution Water treatment |
title | Photocatalytic Removal of Water Emerging Pollutants in an Optimized Packed Bed Photoreactor Using Solar Light |
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