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Influence of Solution Properties and Process Parameters on the Formation and Morphology of YSZ and NiO Ceramic Nanofibers by Electrospinning
The fabrication process of ceramic yttria-stabilized zirconia (YSZ) and nickel oxide nanofibers by electrospinning is reported. The preparation of hollow YSZ nanofibers and aligned nanofiber arrays is also demonstrated. The influence of the process parameters of the electrospinning process, the phys...
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Published in: | Nanomaterials (Basel, Switzerland) Switzerland), 2017-01, Vol.7 (1), p.16-16 |
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description | The fabrication process of ceramic yttria-stabilized zirconia (YSZ) and nickel oxide nanofibers by electrospinning is reported. The preparation of hollow YSZ nanofibers and aligned nanofiber arrays is also demonstrated. The influence of the process parameters of the electrospinning process, the physicochemical properties of the spinning solutions, and the thermal treatment procedure on spinnability and final microstructure of the ceramic fibers was determined. The fiber diameter can be varied from hundreds of nanometers to more than a micrometer by controlling the solution properties of the electrospinning process, while the grain size and surface roughness of the resulting fibers are mainly controlled via the final thermal annealing process. Although most observed phenomena are in qualitative agreement with previous studies on the electrospinning of polymeric nanofibers, one of the main differences is the high ionic strength of ceramic precursor solutions, which may hamper the spinnability. A strategy to control the effective ionic strength of precursor solutions is also presented. |
doi_str_mv | 10.3390/nano7010016 |
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The preparation of hollow YSZ nanofibers and aligned nanofiber arrays is also demonstrated. The influence of the process parameters of the electrospinning process, the physicochemical properties of the spinning solutions, and the thermal treatment procedure on spinnability and final microstructure of the ceramic fibers was determined. The fiber diameter can be varied from hundreds of nanometers to more than a micrometer by controlling the solution properties of the electrospinning process, while the grain size and surface roughness of the resulting fibers are mainly controlled via the final thermal annealing process. Although most observed phenomena are in qualitative agreement with previous studies on the electrospinning of polymeric nanofibers, one of the main differences is the high ionic strength of ceramic precursor solutions, which may hamper the spinnability. A strategy to control the effective ionic strength of precursor solutions is also presented.</description><identifier>ISSN: 2079-4991</identifier><identifier>EISSN: 2079-4991</identifier><identifier>DOI: 10.3390/nano7010016</identifier><identifier>PMID: 28336850</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>alignment ; Ceramic fibers ; Ceramics ; Electrodes ; Electrons ; Electrospinning ; Fabrication ; Fibers ; microstructure ; Morphology ; nanofiber ; Nanofibers ; Nanomaterials ; Nickel ; nickel oxide ; NiO ; Physicochemical properties ; Precursors ; Process parameters ; spinning process ; Strength ; Viscoelasticity ; Viscosity ; YSZ ; Yttria stabilized zirconia</subject><ispartof>Nanomaterials (Basel, Switzerland), 2017-01, Vol.7 (1), p.16-16</ispartof><rights>Copyright MDPI AG 2017</rights><rights>2017 by the authors; licensee MDPI, Basel, Switzerland. 2017</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c541t-9033934ef7483fa3d9119fec7e149b9239c4c82585da8cdb3a63d0934c6e31f3</citedby><cites>FETCH-LOGICAL-c541t-9033934ef7483fa3d9119fec7e149b9239c4c82585da8cdb3a63d0934c6e31f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/1862118517/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/1862118517?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28336850$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cadafalch Gazquez, Gerard</creatorcontrib><creatorcontrib>Smulders, Vera</creatorcontrib><creatorcontrib>Veldhuis, Sjoerd A</creatorcontrib><creatorcontrib>Wieringa, Paul</creatorcontrib><creatorcontrib>Moroni, Lorenzo</creatorcontrib><creatorcontrib>Boukamp, Bernard A</creatorcontrib><creatorcontrib>Ten Elshof, Johan E</creatorcontrib><title>Influence of Solution Properties and Process Parameters on the Formation and Morphology of YSZ and NiO Ceramic Nanofibers by Electrospinning</title><title>Nanomaterials (Basel, Switzerland)</title><addtitle>Nanomaterials (Basel)</addtitle><description>The fabrication process of ceramic yttria-stabilized zirconia (YSZ) and nickel oxide nanofibers by electrospinning is reported. The preparation of hollow YSZ nanofibers and aligned nanofiber arrays is also demonstrated. The influence of the process parameters of the electrospinning process, the physicochemical properties of the spinning solutions, and the thermal treatment procedure on spinnability and final microstructure of the ceramic fibers was determined. The fiber diameter can be varied from hundreds of nanometers to more than a micrometer by controlling the solution properties of the electrospinning process, while the grain size and surface roughness of the resulting fibers are mainly controlled via the final thermal annealing process. Although most observed phenomena are in qualitative agreement with previous studies on the electrospinning of polymeric nanofibers, one of the main differences is the high ionic strength of ceramic precursor solutions, which may hamper the spinnability. A strategy to control the effective ionic strength of precursor solutions is also presented.</description><subject>alignment</subject><subject>Ceramic fibers</subject><subject>Ceramics</subject><subject>Electrodes</subject><subject>Electrons</subject><subject>Electrospinning</subject><subject>Fabrication</subject><subject>Fibers</subject><subject>microstructure</subject><subject>Morphology</subject><subject>nanofiber</subject><subject>Nanofibers</subject><subject>Nanomaterials</subject><subject>Nickel</subject><subject>nickel oxide</subject><subject>NiO</subject><subject>Physicochemical properties</subject><subject>Precursors</subject><subject>Process parameters</subject><subject>spinning process</subject><subject>Strength</subject><subject>Viscoelasticity</subject><subject>Viscosity</subject><subject>YSZ</subject><subject>Yttria stabilized 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properties</topic><topic>Precursors</topic><topic>Process parameters</topic><topic>spinning process</topic><topic>Strength</topic><topic>Viscoelasticity</topic><topic>Viscosity</topic><topic>YSZ</topic><topic>Yttria stabilized zirconia</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cadafalch Gazquez, Gerard</creatorcontrib><creatorcontrib>Smulders, Vera</creatorcontrib><creatorcontrib>Veldhuis, Sjoerd A</creatorcontrib><creatorcontrib>Wieringa, Paul</creatorcontrib><creatorcontrib>Moroni, Lorenzo</creatorcontrib><creatorcontrib>Boukamp, Bernard A</creatorcontrib><creatorcontrib>Ten Elshof, Johan E</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion 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E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of Solution Properties and Process Parameters on the Formation and Morphology of YSZ and NiO Ceramic Nanofibers by Electrospinning</atitle><jtitle>Nanomaterials (Basel, Switzerland)</jtitle><addtitle>Nanomaterials (Basel)</addtitle><date>2017-01-01</date><risdate>2017</risdate><volume>7</volume><issue>1</issue><spage>16</spage><epage>16</epage><pages>16-16</pages><issn>2079-4991</issn><eissn>2079-4991</eissn><abstract>The fabrication process of ceramic yttria-stabilized zirconia (YSZ) and nickel oxide nanofibers by electrospinning is reported. The preparation of hollow YSZ nanofibers and aligned nanofiber arrays is also demonstrated. The influence of the process parameters of the electrospinning process, the physicochemical properties of the spinning solutions, and the thermal treatment procedure on spinnability and final microstructure of the ceramic fibers was determined. The fiber diameter can be varied from hundreds of nanometers to more than a micrometer by controlling the solution properties of the electrospinning process, while the grain size and surface roughness of the resulting fibers are mainly controlled via the final thermal annealing process. Although most observed phenomena are in qualitative agreement with previous studies on the electrospinning of polymeric nanofibers, one of the main differences is the high ionic strength of ceramic precursor solutions, which may hamper the spinnability. A strategy to control the effective ionic strength of precursor solutions is also presented.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>28336850</pmid><doi>10.3390/nano7010016</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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subjects | alignment Ceramic fibers Ceramics Electrodes Electrons Electrospinning Fabrication Fibers microstructure Morphology nanofiber Nanofibers Nanomaterials Nickel nickel oxide NiO Physicochemical properties Precursors Process parameters spinning process Strength Viscoelasticity Viscosity YSZ Yttria stabilized zirconia |
title | Influence of Solution Properties and Process Parameters on the Formation and Morphology of YSZ and NiO Ceramic Nanofibers by Electrospinning |
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