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Relative reactivity of the dinuclear ruthenium complex [CpRu(CO)2]2 with diphenylselenyl sulphide and diphenyl disulphide
[Display omitted] •Reaction of [CpRu(CO)2]2 with diphenyl dichalcogenides.•Photocleavage of metal–metal bond to form [CpRu(CO)2] radicals.•Reaction with selenyl sulphide slower than with disulphide. The reaction of the diruthenium complex [CpRu(CO)2]2 with the diphenyl dichalcogenides was found to p...
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Published in: | Results in Chemistry 2021-01, Vol.3, p.100159, Article 100159 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites |
Online Access: | Get full text |
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Summary: | [Display omitted]
•Reaction of [CpRu(CO)2]2 with diphenyl dichalcogenides.•Photocleavage of metal–metal bond to form [CpRu(CO)2] radicals.•Reaction with selenyl sulphide slower than with disulphide.
The reaction of the diruthenium complex [CpRu(CO)2]2 with the diphenyl dichalcogenides was found to proceed through photoinitiation to the [CpRu(CO)2] radical. Reaction with selenyl sulphide was slower than with disulphide, which has implications for the selective targeting of the enzyme thioredoxin reductase. |
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ISSN: | 2211-7156 2211-7156 |
DOI: | 10.1016/j.rechem.2021.100159 |