Bis(μ-2-phenyl-quinoline-4-carboxyl-ato)bis-[aqua-(1,10-phenanthroline)(2-phenyl-quinoline-4-carboxyl-ato)manganese(II)] dihydrate

In the centrosymmetric dinuclear title complex, [Mn(2)(C(16)H(10)NO(2))(4)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, the Mn(II) cation is in a distorted octa-hedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenyl-quino...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-10, Vol.67 (Pt 10), p.m1464-m1465
Main Authors: Li, Wei-Wei, Bing, Yue, Zha, Mei-Qin, Li, Tian-Hua, Li, Xing
Format: Article
Language:English
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Metal-Organic Papers
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Summary:In the centrosymmetric dinuclear title complex, [Mn(2)(C(16)H(10)NO(2))(4)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O, the Mn(II) cation is in a distorted octa-hedral coordination geometry defined by two N atoms from a 1,10-phenanthroline ligand, one water O atom and three O atoms from three 2-phenyl-quinoline-4-carboxyl-ate anions. A pair of 2-phenyl-quinoline-4-carboxyl-ate anions bridge two Mn cations, forming the dinuclear mol-ecule. An intra-moleculr O-H⋯O hydrogen bond occurs. Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds are present in the crystal structure.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811039341