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Charge self-regulation in 1T'''-MoS2 structure with rich S vacancies for enhanced hydrogen evolution activity
Active electronic states in transition metal dichalcogenides are able to prompt hydrogen evolution by improving hydrogen absorption. However, the development of thermodynamically stable hexagonal 2H-MoS 2 as hydrogen evolution catalyst is likely to be shadowed by its limited active electronic state....
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| Published in: | Nature communications 2022-10, Vol.13 (1), p.5954-5954, Article 5954 |
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| creator | Guo, Xiaowei Song, Erhong Zhao, Wei Xu, Shumao Zhao, Wenli Lei, Yongjiu Fang, Yuqiang Liu, Jianjun Huang, Fuqiang |
| description | Active electronic states in transition metal dichalcogenides are able to prompt hydrogen evolution by improving hydrogen absorption. However, the development of thermodynamically stable hexagonal 2H-MoS
2
as hydrogen evolution catalyst is likely to be shadowed by its limited active electronic state. Herein, the charge self-regulation effect mediated by tuning Mo−Mo bonds and S vacancies is revealed in metastable trigonal MoS
2
(1T'''-MoS
2
) structure, which is favarable for the generation of active electronic states to boost the hydrogen evolution reaction activity. The optimal 1T'''-MoS
2
sample exhibits a low overpotential of 158 mV at 10 mA cm
−2
and a Tafel slope of 74.5 mV dec
−1
in acidic conditions, which are far exceeding the 2H-MoS
2
counterpart (369 mV and 137 mV dec
−1
). Theoretical modeling indicates that the boosted performance is attributed to the formation of massive active electronic states induced by the charge self-regulation effect of Mo−Mo bonds in defective 1T'''-MoS
2
with rich S vacancies.
Metal chalcogenides have shown promising performances for renewable hydrogen evolution and such activities are sensitive to the material electronic structures. Here, authors modulate the electronic properties of molybdenum sulfide in 1T'''-MoS
2
for hydrogen evolution electrocatalysis. |
| doi_str_mv | 10.1038/s41467-022-33636-8 |
| format | article |
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2
as hydrogen evolution catalyst is likely to be shadowed by its limited active electronic state. Herein, the charge self-regulation effect mediated by tuning Mo−Mo bonds and S vacancies is revealed in metastable trigonal MoS
2
(1T'''-MoS
2
) structure, which is favarable for the generation of active electronic states to boost the hydrogen evolution reaction activity. The optimal 1T'''-MoS
2
sample exhibits a low overpotential of 158 mV at 10 mA cm
−2
and a Tafel slope of 74.5 mV dec
−1
in acidic conditions, which are far exceeding the 2H-MoS
2
counterpart (369 mV and 137 mV dec
−1
). Theoretical modeling indicates that the boosted performance is attributed to the formation of massive active electronic states induced by the charge self-regulation effect of Mo−Mo bonds in defective 1T'''-MoS
2
with rich S vacancies.
Metal chalcogenides have shown promising performances for renewable hydrogen evolution and such activities are sensitive to the material electronic structures. Here, authors modulate the electronic properties of molybdenum sulfide in 1T'''-MoS
2
for hydrogen evolution electrocatalysis.</description><identifier>ISSN: 2041-1723</identifier><identifier>EISSN: 2041-1723</identifier><identifier>DOI: 10.1038/s41467-022-33636-8</identifier><identifier>PMID: 36216954</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>140/131 ; 140/133 ; 140/146 ; 147/135 ; 147/137 ; 147/143 ; 639/301/299/886 ; 639/638/161/886 ; 639/925/357/1018 ; Catalysts ; Chalcogenides ; Electron states ; Evolution ; Humanities and Social Sciences ; Hydrogen ; Hydrogen evolution reactions ; Molybdenum ; Molybdenum disulfide ; multidisciplinary ; Science ; Science (multidisciplinary) ; Transition metal compounds</subject><ispartof>Nature communications, 2022-10, Vol.13 (1), p.5954-5954, Article 5954</ispartof><rights>The Author(s) 2022</rights><rights>The Author(s) 2022. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c517t-3c21a5dfcf13353acdc9293ded6f44e04fa5f86f972dd1384669c871e7602e5d3</citedby><cites>FETCH-LOGICAL-c517t-3c21a5dfcf13353acdc9293ded6f44e04fa5f86f972dd1384669c871e7602e5d3</cites><orcidid>0000-0003-2452-6966 ; 0000-0003-0526-5473 ; 0000-0003-2287-3307</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2723291862/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2723291862?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids></links><search><creatorcontrib>Guo, Xiaowei</creatorcontrib><creatorcontrib>Song, Erhong</creatorcontrib><creatorcontrib>Zhao, Wei</creatorcontrib><creatorcontrib>Xu, Shumao</creatorcontrib><creatorcontrib>Zhao, Wenli</creatorcontrib><creatorcontrib>Lei, Yongjiu</creatorcontrib><creatorcontrib>Fang, Yuqiang</creatorcontrib><creatorcontrib>Liu, Jianjun</creatorcontrib><creatorcontrib>Huang, Fuqiang</creatorcontrib><title>Charge self-regulation in 1T'''-MoS2 structure with rich S vacancies for enhanced hydrogen evolution activity</title><title>Nature communications</title><addtitle>Nat Commun</addtitle><description>Active electronic states in transition metal dichalcogenides are able to prompt hydrogen evolution by improving hydrogen absorption. However, the development of thermodynamically stable hexagonal 2H-MoS
2
as hydrogen evolution catalyst is likely to be shadowed by its limited active electronic state. Herein, the charge self-regulation effect mediated by tuning Mo−Mo bonds and S vacancies is revealed in metastable trigonal MoS
2
(1T'''-MoS
2
) structure, which is favarable for the generation of active electronic states to boost the hydrogen evolution reaction activity. The optimal 1T'''-MoS
2
sample exhibits a low overpotential of 158 mV at 10 mA cm
−2
and a Tafel slope of 74.5 mV dec
−1
in acidic conditions, which are far exceeding the 2H-MoS
2
counterpart (369 mV and 137 mV dec
−1
). Theoretical modeling indicates that the boosted performance is attributed to the formation of massive active electronic states induced by the charge self-regulation effect of Mo−Mo bonds in defective 1T'''-MoS
2
with rich S vacancies.
Metal chalcogenides have shown promising performances for renewable hydrogen evolution and such activities are sensitive to the material electronic structures. Here, authors modulate the electronic properties of molybdenum sulfide in 1T'''-MoS
2
for hydrogen evolution electrocatalysis.</description><subject>140/131</subject><subject>140/133</subject><subject>140/146</subject><subject>147/135</subject><subject>147/137</subject><subject>147/143</subject><subject>639/301/299/886</subject><subject>639/638/161/886</subject><subject>639/925/357/1018</subject><subject>Catalysts</subject><subject>Chalcogenides</subject><subject>Electron states</subject><subject>Evolution</subject><subject>Humanities and Social Sciences</subject><subject>Hydrogen</subject><subject>Hydrogen evolution reactions</subject><subject>Molybdenum</subject><subject>Molybdenum disulfide</subject><subject>multidisciplinary</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Transition metal 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titles)</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Nature communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Xiaowei</au><au>Song, Erhong</au><au>Zhao, Wei</au><au>Xu, Shumao</au><au>Zhao, Wenli</au><au>Lei, Yongjiu</au><au>Fang, Yuqiang</au><au>Liu, Jianjun</au><au>Huang, Fuqiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Charge self-regulation in 1T'''-MoS2 structure with rich S vacancies for enhanced hydrogen evolution activity</atitle><jtitle>Nature communications</jtitle><stitle>Nat Commun</stitle><date>2022-10-10</date><risdate>2022</risdate><volume>13</volume><issue>1</issue><spage>5954</spage><epage>5954</epage><pages>5954-5954</pages><artnum>5954</artnum><issn>2041-1723</issn><eissn>2041-1723</eissn><abstract>Active electronic states in transition metal dichalcogenides are able to prompt hydrogen evolution by improving hydrogen absorption. However, the development of thermodynamically stable hexagonal 2H-MoS
2
as hydrogen evolution catalyst is likely to be shadowed by its limited active electronic state. Herein, the charge self-regulation effect mediated by tuning Mo−Mo bonds and S vacancies is revealed in metastable trigonal MoS
2
(1T'''-MoS
2
) structure, which is favarable for the generation of active electronic states to boost the hydrogen evolution reaction activity. The optimal 1T'''-MoS
2
sample exhibits a low overpotential of 158 mV at 10 mA cm
−2
and a Tafel slope of 74.5 mV dec
−1
in acidic conditions, which are far exceeding the 2H-MoS
2
counterpart (369 mV and 137 mV dec
−1
). Theoretical modeling indicates that the boosted performance is attributed to the formation of massive active electronic states induced by the charge self-regulation effect of Mo−Mo bonds in defective 1T'''-MoS
2
with rich S vacancies.
Metal chalcogenides have shown promising performances for renewable hydrogen evolution and such activities are sensitive to the material electronic structures. Here, authors modulate the electronic properties of molybdenum sulfide in 1T'''-MoS
2
for hydrogen evolution electrocatalysis.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>36216954</pmid><doi>10.1038/s41467-022-33636-8</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0003-2452-6966</orcidid><orcidid>https://orcid.org/0000-0003-0526-5473</orcidid><orcidid>https://orcid.org/0000-0003-2287-3307</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | 140/131 140/133 140/146 147/135 147/137 147/143 639/301/299/886 639/638/161/886 639/925/357/1018 Catalysts Chalcogenides Electron states Evolution Humanities and Social Sciences Hydrogen Hydrogen evolution reactions Molybdenum Molybdenum disulfide multidisciplinary Science Science (multidisciplinary) Transition metal compounds |
| title | Charge self-regulation in 1T'''-MoS2 structure with rich S vacancies for enhanced hydrogen evolution activity |
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