catena-Poly[(S)-2-methylpiperazine-1,4-diium [[trichloridobismuthate(III)]-di- #956;-chlorido]]

In the crystal structure of the title compound, {(C5H14N2)[BiCl5]}n, the BiIII cation is coordinated by six Cl− anions in a distorted octahedral geometry. Two Cl− anions bridge neighboring BiIII cations, forming a zigzag polymeric chain along the a axis. The discrete methylpipera...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-09, Vol.66 (9), p.m1079-m1079
Main Author: Zong-Ling Ru
Format: Article
Language:English
Online Access:Get full text
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Summary:In the crystal structure of the title compound, {(C5H14N2)[BiCl5]}n, the BiIII cation is coordinated by six Cl− anions in a distorted octahedral geometry. Two Cl− anions bridge neighboring BiIII cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperazinediium cation adopts a normal chair conformation and is linked to the polymeric chains by N—H...Cl hydrogen bonding.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810031417