Liquid-crystalline behavior on dumbbell-shaped colloids and the observation of chiral blue phases

Colloidal liquid crystals are an emerging class of soft materials that naturally combine the unique properties of both liquid crystal molecules and colloidal particles. Chiral liquid crystal blue phases are attractive for use in fast optical displays and electrooptical devices, but the construction...

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Bibliographic Details
Published in:Nature communications 2022-09, Vol.13 (1), p.5549-5549, Article 5549
Main Authors: Chen, Guangdong, Pei, Hanwen, Zhang, Xuefei, Shi, Wei, Liu, Mingjie, Faul, Charl F. J., Yang, Bai, Zhao, Yan, Liu, Kun, Lu, Zhongyuan, Nie, Zhihong, Yang, Yang
Format: Article
Language:English
Subjects:
119/118
147/135
639/301/923/916
639/301/923/966
Colloids
Columns (structural)
Construction
Crystal structure
Crystals
Functional materials
Humanities and Social Sciences
Liquid crystals
multidisciplinary
Nematic crystals
Phase diagrams
Phases
Photonic crystals
Science
Science (multidisciplinary)
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Summary:Colloidal liquid crystals are an emerging class of soft materials that naturally combine the unique properties of both liquid crystal molecules and colloidal particles. Chiral liquid crystal blue phases are attractive for use in fast optical displays and electrooptical devices, but the construction of blue phases is limited to a few chiral building blocks and the formation of blue phases from achiral ones is often counterintuitive. Herein we demonstrate that achiral dumbbell-shaped colloids can assemble into a rich variety of characteristic liquid crystal phases, including nematic phases with lock structures, smectic phase, and particularly experimental observation of blue phase III with double-twisted chiral columns. Phase diagrams from experiments and simulations show that the existence and stable regions of different liquid crystal phases are strongly dependent on the geometrical parameters of dumbbell-shaped colloids. This work paves a new route to the design and construction of blue phases for photonic applications. Colloidal liquid crystals account for various applications due to the combination of characteristics relevant for liquid crystals and colloids. The authors elaborate the impact of concave geometry on the properties of colloidal liquid crystals for development of functional materials.
ISSN:2041-1723
2041-1723
DOI:10.1038/s41467-022-33125-y