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Crystal structure of (aceto-nitrile-κN)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ2N,N')copper(I)
The Cu I atom in the molecular structure of the title compound exhibits a distorted tetrahedral coordination sphere, defined by two N atoms of the chelating ligand, one N atom of the acetonitrile ligand and one iodide ligand. In the mononuclear title complex, [CuI(C 2 H 3 N)(C 26 H 24 N 2 )], the...
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| Published in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2016-12, Vol.72 (Pt 12), p.1845-1847 |
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| Language: | English |
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| container_end_page | 1847 |
| container_issue | Pt 12 |
| container_start_page | 1845 |
| container_title | Acta crystallographica. Section E, Crystallographic communications |
| container_volume | 72 |
| creator | Al-Najjar, Nada Solan, Gregory A Singh, Kuldip |
| description | The Cu
I
atom in the molecular structure of the title compound exhibits a distorted tetrahedral coordination sphere, defined by two N atoms of the chelating ligand, one N atom of the acetonitrile ligand and one iodide ligand.
In the mononuclear title complex, [CuI(C
2
H
3
N)(C
26
H
24
N
2
)], the Cu
I
ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodide ligand. Within the complex, there are weak intramolecular C—H⋯N hydrogen bonds, while weak intermolecular C—H⋯I interactions between complex molecules, help to facilitate a three-dimensional network. |
| doi_str_mv | 10.1107/s2056989016018685 |
| format | article |
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I
atom in the molecular structure of the title compound exhibits a distorted tetrahedral coordination sphere, defined by two N atoms of the chelating ligand, one N atom of the acetonitrile ligand and one iodide ligand.
In the mononuclear title complex, [CuI(C
2
H
3
N)(C
26
H
24
N
2
)], the Cu
I
ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodide ligand. Within the complex, there are weak intramolecular C—H⋯N hydrogen bonds, while weak intermolecular C—H⋯I interactions between complex molecules, help to facilitate a three-dimensional network.</description><identifier>ISSN: 2056-9890</identifier><identifier>EISSN: 2056-9890</identifier><identifier>DOI: 10.1107/s2056989016018685</identifier><identifier>PMID: 27980846</identifier><language>eng</language><publisher>International Union of Crystallography</publisher><subject>2-imino-6-(naphthalen-1-yl)pyridine ; bidentate ligand ; copper(I) complex ; crystal structure ; iodide ; Research Communications ; Schiff base</subject><ispartof>Acta crystallographica. Section E, Crystallographic communications, 2016-12, Vol.72 (Pt 12), p.1845-1847</ispartof><rights>Al-Najjar et al. 2016 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137624/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137624/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids></links><search><creatorcontrib>Al-Najjar, Nada</creatorcontrib><creatorcontrib>Solan, Gregory A</creatorcontrib><creatorcontrib>Singh, Kuldip</creatorcontrib><title>Crystal structure of (aceto-nitrile-κN)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ2N,N')copper(I)</title><title>Acta crystallographica. Section E, Crystallographic communications</title><description>The Cu
I
atom in the molecular structure of the title compound exhibits a distorted tetrahedral coordination sphere, defined by two N atoms of the chelating ligand, one N atom of the acetonitrile ligand and one iodide ligand.
In the mononuclear title complex, [CuI(C
2
H
3
N)(C
26
H
24
N
2
)], the Cu
I
ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodide ligand. Within the complex, there are weak intramolecular C—H⋯N hydrogen bonds, while weak intermolecular C—H⋯I interactions between complex molecules, help to facilitate a three-dimensional network.</description><subject>2-imino-6-(naphthalen-1-yl)pyridine</subject><subject>bidentate ligand</subject><subject>copper(I) complex</subject><subject>crystal structure</subject><subject>iodide</subject><subject>Research Communications</subject><subject>Schiff base</subject><issn>2056-9890</issn><issn>2056-9890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNpVkUtu1EAQhi0EIlHIAdjNDo80Df1-bJDQiMdI0bCBFUJW212OO2q7TbsdyUKcgBtxCM6EJ8mCrKr0_X99myqKlwS_JgSrNxPFQhptMJGYaKnFk-L8hNCJPf1vPysup-kGY0y4YFLQ58UZVUZjzeV58XuflinbsJlymps8J9jEdlPaBnJEg8_JB0B__xy3PjrvIiopKgc7drmzAQZE0BK2SKKfBH0r6Y7vJFpPUA-5WwIau7WyFnzvh_j9jv1C45K888PJSo-746ttE8cRUnnYviietTZMcPkwL4qvH95_2X9CV58_HvbvrpAjRgkka6O0AklVrYE2tmYCFFdKMmwJcYZhDNoxRnhLLTGuxbbFUggQQmBea3ZRHO69Ltqbaky-t2mpovXVHYjpurIp-yZAZaE1HJR1kivuiDRM0Zo22jIJusVkdb29d41z3YNrYMjJhkfSx8ngu-o63laCMCUpXwXlgyDFHzNMuer91EAIdoA4TxXRglCt1o-xf6etmPg</recordid><startdate>20161201</startdate><enddate>20161201</enddate><creator>Al-Najjar, Nada</creator><creator>Solan, Gregory A</creator><creator>Singh, Kuldip</creator><general>International Union of Crystallography</general><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope></search><sort><creationdate>20161201</creationdate><title>Crystal structure of (aceto-nitrile-κN)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ2N,N')copper(I)</title><author>Al-Najjar, Nada ; Solan, Gregory A ; Singh, Kuldip</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-d1975-6b9787e627b8e2cab35e7477630a11d9300e8d3314f2a19df0af0655e55504b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>2-imino-6-(naphthalen-1-yl)pyridine</topic><topic>bidentate ligand</topic><topic>copper(I) complex</topic><topic>crystal structure</topic><topic>iodide</topic><topic>Research Communications</topic><topic>Schiff base</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Al-Najjar, Nada</creatorcontrib><creatorcontrib>Solan, Gregory A</creatorcontrib><creatorcontrib>Singh, Kuldip</creatorcontrib><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><collection>Directory of Open Access Journals</collection><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Najjar, Nada</au><au>Solan, Gregory A</au><au>Singh, Kuldip</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of (aceto-nitrile-κN)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ2N,N')copper(I)</atitle><jtitle>Acta crystallographica. Section E, Crystallographic communications</jtitle><date>2016-12-01</date><risdate>2016</risdate><volume>72</volume><issue>Pt 12</issue><spage>1845</spage><epage>1847</epage><pages>1845-1847</pages><issn>2056-9890</issn><eissn>2056-9890</eissn><abstract>The Cu
I
atom in the molecular structure of the title compound exhibits a distorted tetrahedral coordination sphere, defined by two N atoms of the chelating ligand, one N atom of the acetonitrile ligand and one iodide ligand.
In the mononuclear title complex, [CuI(C
2
H
3
N)(C
26
H
24
N
2
)], the Cu
I
ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodide ligand. Within the complex, there are weak intramolecular C—H⋯N hydrogen bonds, while weak intermolecular C—H⋯I interactions between complex molecules, help to facilitate a three-dimensional network.</abstract><pub>International Union of Crystallography</pub><pmid>27980846</pmid><doi>10.1107/s2056989016018685</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 2056-9890 |
| ispartof | Acta crystallographica. Section E, Crystallographic communications, 2016-12, Vol.72 (Pt 12), p.1845-1847 |
| issn | 2056-9890 2056-9890 |
| language | eng |
| recordid | cdi_doaj_primary_oai_doaj_org_article_aef94e7ad6474d169372b2c8a36e8f01 |
| source | IngentaConnect Journals; PubMed Central |
| subjects | 2-imino-6-(naphthalen-1-yl)pyridine bidentate ligand copper(I) complex crystal structure iodide Research Communications Schiff base |
| title | Crystal structure of (aceto-nitrile-κN)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ2N,N')copper(I) |
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