Iron(III)-Mediated Rapid Radical-Type Three-Component Deuteration of Quinoxalinones With Olefins and NaBD4

Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD4 is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones. In this transformation, a radical pathway is involved according t...

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Bibliographic Details
Published in:Frontiers in chemistry 2020-08, Vol.8, p.606-606
Main Authors: Li, Wanmei, Cai, Heng, Huang, Lin, He, Lei, Zhang, Yilan, Xu, Jun, Zhang, Pengfei
Format: Article
Language:English
Subjects:
alkenes
Chemistry
deuteration
quinoxalinones
radical pathway
three-component
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Summary:Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD4 is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones. In this transformation, a radical pathway is involved according to the results of control experiments.
ISSN:2296-2646
2296-2646
DOI:10.3389/fchem.2020.00606