Liquid-Phase Hydrogenation of Maleic Acid over Pd/Al2O3 Catalysts Prepared via Deposition–Precipitation Method

• Published in: Energies (Basel) 2019-01, Vol.12 (2), p.284
• Main Authors: Byun, Mi Yeon, Ji Sun Kim, Jae Ho Baek, Park, Dae-Won, Man Sig Lee
• Format: Article
• Language: English
• Subjects: Acids; Aluminum oxide; Catalysts; Catalytic activity; Chemical industry; Climate change; Conversion; Dispersion; Fumaric acid; Gamma phase; Global warming; High temperature; Hydrogen storage; Hydrogenation; Industrial pollution; Industrial wastes; Liquid phases; Maleic acid; Particle size; Pd catalyst; Petrochemicals industry; Physicochemical properties; Pressure; Reaction time; Renewable resources; Retention; Selectivity; Succinic acid; supported catalyst; Sustainable yield; Temperature
• ISSN: 1996-1073; 1996-1073
• DOI: 10.3390/en12020284

Succinic acid (SA) is a valuable raw material obtained by hydrogenation of maleic acid (MA). The product selectivity of this reaction is highly dependent on the reaction conditions. This study therefore investigated the effect of the reaction temperature, hydrogen pressure, and reaction time on the liquid-phase hydrogenation of MA by a Pd/Al2O3 catalyst. Complete conversion of MA and 100% selectivity for SA were achieved at a temperature of 90 °C, H2 pressure of 5 bar, and reaction time of 90 min. Fumaric acid (FA) was formed as an intermediate material by hydrogenation of MA under nonoptimal conditions. The impact of the percentage of Pd dispersion and phase of the Al2O3 support (γ, θ + α, and α) was also examined. The Pd/Al2O3 catalyst with 29.8% dispersion of Pd and γ phase of Al2O3 exhibited the best catalytic performance. Thus, catalytic activity depends not only on the amount of Pd dispersion but also on the physicochemical properties of Al2O3.