Half-Sandwich Nickelacarboranes Derived from [7-(MeO(CH2)2S)-7,8-C2B9H11]

New carboranyl thioethers 1-MeO(CH2)nS-1,2-C2B10H11 (n = 2, 3) were prepared by the alkylation of the trimethylammonium salt of 1-mercapto-ortho-carborane with 1-bromo- 2-methoxyethane and 1-bromo-3-methoxypropane, respectively. Their deboronation with cesium fluoride in ethanol gave the correspondi...

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Published in:Inorganics 2023-03, Vol.11 (3), p.127
Main Authors: Semyonov, Dmitriy K., Stogniy, Marina Yu, Suponitsky, Kyrill Yu, Sivaev, Igor B.
Format: Article
Language:English
Subjects:
Alkylation
Carbon
Carborane
carboranyl thioethers
Catalysis
Cesium
Cesium fluorides
Crystal structure
Ethanol
half-sandwich complexes
Ligands
Molecular structure
Nickel chloride
nickelacarboranes
nido-carborane ligands
Phosphine
phosphine ligands
Phosphines
Single crystals
Solvents
Symmetry
synthesis
Thioethers
X-ray diffraction
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description New carboranyl thioethers 1-MeO(CH2)nS-1,2-C2B10H11 (n = 2, 3) were prepared by the alkylation of the trimethylammonium salt of 1-mercapto-ortho-carborane with 1-bromo- 2-methoxyethane and 1-bromo-3-methoxypropane, respectively. Their deboronation with cesium fluoride in ethanol gave the corresponding nido-carboranes Cs[7-MeO(CH2)nS-7,8-C2B9H11] (n = 2, 3). The reactions of Cs[7-MeO(CH2)2S-7,8-C2B9H11] with various nickel(II) phosphine complexes [(dppe)NiCl2] and [(R’R2P)2NiCl2] (R = R’ = Ph, Bu; R = Me, R’ = Ph; R = Ph, R’ = Me, Et) were studied and a series of nickelacarboranes 3,3-dppe-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 and 3,3- (R’R2P)2-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 (R = R’ = Bu; R = Me, R’ = Ph; R = Ph, R’ = Me, Et) was prepared. The molecular crystal structure of 3,3-dppe-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 was determined by single-crystal X-ray diffraction.
doi_str_mv 10.3390/inorganics11030127
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Their deboronation with cesium fluoride in ethanol gave the corresponding nido-carboranes Cs[7-MeO(CH2)nS-7,8-C2B9H11] (n = 2, 3). The reactions of Cs[7-MeO(CH2)2S-7,8-C2B9H11] with various nickel(II) phosphine complexes [(dppe)NiCl2] and [(R’R2P)2NiCl2] (R = R’ = Ph, Bu; R = Me, R’ = Ph; R = Ph, R’ = Me, Et) were studied and a series of nickelacarboranes 3,3-dppe-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 and 3,3- (R’R2P)2-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 (R = R’ = Bu; R = Me, R’ = Ph; R = Ph, R’ = Me, Et) was prepared. The molecular crystal structure of 3,3-dppe-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 was determined by single-crystal X-ray diffraction.</description><identifier>ISSN: 2304-6740</identifier><identifier>EISSN: 2304-6740</identifier><identifier>DOI: 10.3390/inorganics11030127</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Alkylation ; Carbon ; Carborane ; carboranyl thioethers ; Catalysis ; Cesium ; Cesium fluorides ; Crystal structure ; Ethanol ; half-sandwich complexes ; Ligands ; Molecular structure ; Nickel chloride ; nickelacarboranes ; nido-carborane ligands ; Phosphine ; phosphine ligands ; Phosphines ; Single crystals ; Solvents ; Symmetry ; synthesis ; Thioethers ; X-ray diffraction</subject><ispartof>Inorganics, 2023-03, Vol.11 (3), p.127</ispartof><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. 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Their deboronation with cesium fluoride in ethanol gave the corresponding nido-carboranes Cs[7-MeO(CH2)nS-7,8-C2B9H11] (n = 2, 3). The reactions of Cs[7-MeO(CH2)2S-7,8-C2B9H11] with various nickel(II) phosphine complexes [(dppe)NiCl2] and [(R’R2P)2NiCl2] (R = R’ = Ph, Bu; R = Me, R’ = Ph; R = Ph, R’ = Me, Et) were studied and a series of nickelacarboranes 3,3-dppe-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 and 3,3- (R’R2P)2-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 (R = R’ = Bu; R = Me, R’ = Ph; R = Ph, R’ = Me, Et) was prepared. The molecular crystal structure of 3,3-dppe-1-MeO(CH2)2S-closo-3,1,2-NiC2B9H10 was determined by single-crystal X-ray diffraction.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/inorganics11030127</doi><orcidid>https://orcid.org/0000-0003-0617-0118</orcidid><orcidid>https://orcid.org/0000-0002-5442-367X</orcidid><oa>free_for_read</oa></addata></record>
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subjects Alkylation
Carbon
Carborane
carboranyl thioethers
Catalysis
Cesium
Cesium fluorides
Crystal structure
Ethanol
half-sandwich complexes
Ligands
Molecular structure
Nickel chloride
nickelacarboranes
nido-carborane ligands
Phosphine
phosphine ligands
Phosphines
Single crystals
Solvents
Symmetry
synthesis
Thioethers
X-ray diffraction
title Half-Sandwich Nickelacarboranes Derived from [7-(MeO(CH2)2S)-7,8-C2B9H11]
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