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An 80-million-year sulphur isotope record of pyrite burial over the Permian–Triassic
Despite the extensive use of sulphur isotope ratios (δ 34 S) for understanding ancient biogeochemical cycles, many studies focus on specific time-points of interest, such as the end-Permian mass extinction (EPME). We have generated an 80 million-year Permian–Triassic δ 34 S evap curve from the Stait...
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Published in: | Scientific reports 2022-10, Vol.12 (1), p.17370-17370, Article 17370 |
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creator | Salisbury, Jack Gröcke, Darren R. Cheung, H. D. R. Ashleigh Kump, Lee R. McKie, Tom Ruffell, Alastair |
description | Despite the extensive use of sulphur isotope ratios (δ
34
S) for understanding ancient biogeochemical cycles, many studies focus on specific time-points of interest, such as the end-Permian mass extinction (EPME). We have generated an 80 million-year Permian–Triassic δ
34
S
evap
curve from the Staithes S-20 borehole, Yorkshire, England. The Staithes δ
34
S
evap
record replicates the major features of the global curve, while confirming a new excursion at the Olenekian/Anisian boundary at ~ 247 million years ago. We incorporate the resultant δ
34
S
evap
curve into a sulphur isotope box model. Our modelling approach reveals three significant pyrite burial events (i.e. PBEs) in the Triassic. In particular, it predicts a significant biogeochemical response across the EPME, resulting in a substantial increase in pyrite burial, possibly driven by Siberian Traps volcanism. Our model suggests that after ~ 10 million years pyrite burial achieves relative long-term stability until the latest Triassic. |
doi_str_mv | 10.1038/s41598-022-21542-4 |
format | article |
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34
S) for understanding ancient biogeochemical cycles, many studies focus on specific time-points of interest, such as the end-Permian mass extinction (EPME). We have generated an 80 million-year Permian–Triassic δ
34
S
evap
curve from the Staithes S-20 borehole, Yorkshire, England. The Staithes δ
34
S
evap
record replicates the major features of the global curve, while confirming a new excursion at the Olenekian/Anisian boundary at ~ 247 million years ago. We incorporate the resultant δ
34
S
evap
curve into a sulphur isotope box model. Our modelling approach reveals three significant pyrite burial events (i.e. PBEs) in the Triassic. In particular, it predicts a significant biogeochemical response across the EPME, resulting in a substantial increase in pyrite burial, possibly driven by Siberian Traps volcanism. Our model suggests that after ~ 10 million years pyrite burial achieves relative long-term stability until the latest Triassic.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-022-21542-4</identifier><identifier>PMID: 36253491</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>704/2151/209 ; 704/2151/213 ; 704/2151/3930 ; 704/47/4112 ; Age ; Biogeochemical cycles ; Biogeochemistry ; Boreholes ; Burial ; Carbon ; Extinction ; Extinction, Biological ; Fossils ; Humanities and Social Sciences ; Iron ; Mass extinctions ; multidisciplinary ; Permian ; Pyrite ; Science ; Science (multidisciplinary) ; Sulfides ; Sulfur ; Sulfur Isotopes ; Trends ; Triassic</subject><ispartof>Scientific reports, 2022-10, Vol.12 (1), p.17370-17370, Article 17370</ispartof><rights>The Author(s) 2022</rights><rights>2022. The Author(s).</rights><rights>The Author(s) 2022. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c540t-1a50de368bb3da13bdddeb0026fa9c5b3b0a581bd661393305e0c5c52a5fee33</citedby><cites>FETCH-LOGICAL-c540t-1a50de368bb3da13bdddeb0026fa9c5b3b0a581bd661393305e0c5c52a5fee33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2725460823/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2725460823?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36253491$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Salisbury, Jack</creatorcontrib><creatorcontrib>Gröcke, Darren R.</creatorcontrib><creatorcontrib>Cheung, H. D. R. Ashleigh</creatorcontrib><creatorcontrib>Kump, Lee R.</creatorcontrib><creatorcontrib>McKie, Tom</creatorcontrib><creatorcontrib>Ruffell, Alastair</creatorcontrib><title>An 80-million-year sulphur isotope record of pyrite burial over the Permian–Triassic</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Despite the extensive use of sulphur isotope ratios (δ
34
S) for understanding ancient biogeochemical cycles, many studies focus on specific time-points of interest, such as the end-Permian mass extinction (EPME). We have generated an 80 million-year Permian–Triassic δ
34
S
evap
curve from the Staithes S-20 borehole, Yorkshire, England. The Staithes δ
34
S
evap
record replicates the major features of the global curve, while confirming a new excursion at the Olenekian/Anisian boundary at ~ 247 million years ago. We incorporate the resultant δ
34
S
evap
curve into a sulphur isotope box model. Our modelling approach reveals three significant pyrite burial events (i.e. PBEs) in the Triassic. In particular, it predicts a significant biogeochemical response across the EPME, resulting in a substantial increase in pyrite burial, possibly driven by Siberian Traps volcanism. Our model suggests that after ~ 10 million years pyrite burial achieves relative long-term stability until the latest Triassic.</description><subject>704/2151/209</subject><subject>704/2151/213</subject><subject>704/2151/3930</subject><subject>704/47/4112</subject><subject>Age</subject><subject>Biogeochemical cycles</subject><subject>Biogeochemistry</subject><subject>Boreholes</subject><subject>Burial</subject><subject>Carbon</subject><subject>Extinction</subject><subject>Extinction, Biological</subject><subject>Fossils</subject><subject>Humanities and Social Sciences</subject><subject>Iron</subject><subject>Mass extinctions</subject><subject>multidisciplinary</subject><subject>Permian</subject><subject>Pyrite</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Sulfides</subject><subject>Sulfur</subject><subject>Sulfur Isotopes</subject><subject>Trends</subject><subject>Triassic</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNp9kstu1DAUhiMEolXpC7BAkdiwCdjHlyQbpKriUqkSLEZsLV9OZjxK4mAnlWbHO_CGPAnupJSWBd7Y8vnPZ__2XxQvKXlLCWveJU5F21QEoAIqOFT8SXEKhIsKGMDTB-uT4jylPclDQMtp-7w4YRIE4y09Lb5djGVDqsH3vQ9jdUAdy7T0026JpU9hDhOWEW2IrgxdOR2in7E0S_S6L8MNxnLeYfkV4-D1-OvHz00upOTti-JZp_uE53fzWbH5-GFz-bm6_vLp6vLiurKCk7miWhCHTDbGMKcpM845NISA7HRrhWGGaNFQ46SkrGWMCCRWWAFadIiMnRVXK9YFvVdT9IOOBxW0V8eNELdKx9nbHpXhwLRD0jWm4wCgGasRaAOtqWmju8x6v7KmxQzoLI5z1P0j6OPK6HdqG25UK2opa5kBb-4AMXxfMM1q8Mli3-sRw5IU1CBktt2KLH39j3QfljjmlzqquCQN3LqDVWVjSClid38ZStRtCNQaApVDoI4hUDw3vXpo477lz5dnAVsFKZfGLca_Z_8H-xsNgb4e</recordid><startdate>20221017</startdate><enddate>20221017</enddate><creator>Salisbury, Jack</creator><creator>Gröcke, Darren R.</creator><creator>Cheung, H. 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D. R. Ashleigh ; Kump, Lee R. ; McKie, Tom ; Ruffell, Alastair</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c540t-1a50de368bb3da13bdddeb0026fa9c5b3b0a581bd661393305e0c5c52a5fee33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>704/2151/209</topic><topic>704/2151/213</topic><topic>704/2151/3930</topic><topic>704/47/4112</topic><topic>Age</topic><topic>Biogeochemical cycles</topic><topic>Biogeochemistry</topic><topic>Boreholes</topic><topic>Burial</topic><topic>Carbon</topic><topic>Extinction</topic><topic>Extinction, Biological</topic><topic>Fossils</topic><topic>Humanities and Social Sciences</topic><topic>Iron</topic><topic>Mass extinctions</topic><topic>multidisciplinary</topic><topic>Permian</topic><topic>Pyrite</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>Sulfides</topic><topic>Sulfur</topic><topic>Sulfur Isotopes</topic><topic>Trends</topic><topic>Triassic</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Salisbury, Jack</creatorcontrib><creatorcontrib>Gröcke, Darren R.</creatorcontrib><creatorcontrib>Cheung, H. 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D. R. Ashleigh</au><au>Kump, Lee R.</au><au>McKie, Tom</au><au>Ruffell, Alastair</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An 80-million-year sulphur isotope record of pyrite burial over the Permian–Triassic</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2022-10-17</date><risdate>2022</risdate><volume>12</volume><issue>1</issue><spage>17370</spage><epage>17370</epage><pages>17370-17370</pages><artnum>17370</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Despite the extensive use of sulphur isotope ratios (δ
34
S) for understanding ancient biogeochemical cycles, many studies focus on specific time-points of interest, such as the end-Permian mass extinction (EPME). We have generated an 80 million-year Permian–Triassic δ
34
S
evap
curve from the Staithes S-20 borehole, Yorkshire, England. The Staithes δ
34
S
evap
record replicates the major features of the global curve, while confirming a new excursion at the Olenekian/Anisian boundary at ~ 247 million years ago. We incorporate the resultant δ
34
S
evap
curve into a sulphur isotope box model. Our modelling approach reveals three significant pyrite burial events (i.e. PBEs) in the Triassic. In particular, it predicts a significant biogeochemical response across the EPME, resulting in a substantial increase in pyrite burial, possibly driven by Siberian Traps volcanism. Our model suggests that after ~ 10 million years pyrite burial achieves relative long-term stability until the latest Triassic.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>36253491</pmid><doi>10.1038/s41598-022-21542-4</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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source | PubMed Central(OpenAccess); Publicly Available Content (ProQuest); Free Full-Text Journals in Chemistry; Springer Nature - nature.com Journals - Fully Open Access |
subjects | 704/2151/209 704/2151/213 704/2151/3930 704/47/4112 Age Biogeochemical cycles Biogeochemistry Boreholes Burial Carbon Extinction Extinction, Biological Fossils Humanities and Social Sciences Iron Mass extinctions multidisciplinary Permian Pyrite Science Science (multidisciplinary) Sulfides Sulfur Sulfur Isotopes Trends Triassic |
title | An 80-million-year sulphur isotope record of pyrite burial over the Permian–Triassic |
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