Bis(1,10-phenanthroline-κ 2 N , N ′)(sulfato-κ O )zinc(II) propane-1,2-diol monosolvate

In the title compound, [Zn(SO 4 )(C 12 H 8 N 2 ) 2 ]·C 3 H 8 O 2 , the Zn II ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn II ion lies on a twofold rotat...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-10, Vol.69 (10), p.m561-m561
Main Author: Zhong, Kai-Long
Format: Article
Language:English
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Metal-Organic Papers
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Summary:In the title compound, [Zn(SO 4 )(C 12 H 8 N 2 ) 2 ]·C 3 H 8 O 2 , the Zn II ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn II ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol mol­ecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N 2 C 2 groups is 83.26 (13)°. In the crystal, the complex mol­ecule and the propane-1,2-diol mol­ecule are connected through a pair of O—H⋯O hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053681302610X