Loading…
1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea
In the title molecule, C 18 H 20 F 2 N 2 O 2 S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) Å, respectively; the dihedral angle between these two planes is 71....
Saved in:
| Published in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-06, Vol.68 (6), p.o1597-o1597 |
|---|---|
| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Citations: | Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c354t-e4e76e2d01d543dc6493d463ce078f9f2a11bd336839a3e517c355d62d123e653 |
|---|---|
| cites | |
| container_end_page | o1597 |
| container_issue | 6 |
| container_start_page | o1597 |
| container_title | Acta crystallographica. Section E, Structure reports online |
| container_volume | 68 |
| creator | Mohamed, Shaaban K. Jaber, Abdel-Aal M. Saeed, Sohail Ahmad, Khuram Shahzad Wong, Wing-Tak |
| description | In the title molecule, C
18
H
20
F
2
N
2
O
2
S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) Å, respectively; the dihedral angle between these two planes is 71.03 (6)°. An intramolecular N—H...O hydrogen bond occurs. In the crystal, N—H...O and O—H...S hydrogen bonds connect the molecules into chains running diagonally across the
bc
plane. C—H...S and C—H...F contacts are also observed. |
| doi_str_mv | 10.1107/S1600536812018806 |
| format | article |
| fullrecord | <record><control><sourceid>doaj_cross</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_b6c1366d7bbf437eb3caaf762706e685</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_b6c1366d7bbf437eb3caaf762706e685</doaj_id><sourcerecordid>oai_doaj_org_article_b6c1366d7bbf437eb3caaf762706e685</sourcerecordid><originalsourceid>FETCH-LOGICAL-c354t-e4e76e2d01d543dc6493d463ce078f9f2a11bd336839a3e517c355d62d123e653</originalsourceid><addsrcrecordid>eNplkNtKAzEQhoMoWKsP4BtUMJrJZCfby1I8FApeqNchm4Pdsm1Kdgvu29u1IoJXM3z88zH8jF2DuAMQ-v4VSIgCqQQpoCwFnbDRgPjATv_s5-yibddCAGkJIzYHPpl5u7Hbzm458L5xNldp2zc3HPlE3hL3dWz2KSeu-Kr3OX32u1UYAt2qTvsc7CU7i7Zpw9XPHLP3x4e3-TNfvjwt5rMld1iojgcVNAXpBfhCoXekpugVoQtCl3EapQWoPB5-xKnFUIA-3BWepAeJgQocs8XR65Ndm12uNzb3JtnafIOUP4zNXe2aYCpygEReV1VUqEOFztqoSWpBgcrBBUeXy6ltc4i_PhBmaNT8axS_AIf9ZjU</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea</title><source>Open Access: PubMed Central</source><creator>Mohamed, Shaaban K. ; Jaber, Abdel-Aal M. ; Saeed, Sohail ; Ahmad, Khuram Shahzad ; Wong, Wing-Tak</creator><creatorcontrib>Mohamed, Shaaban K. ; Jaber, Abdel-Aal M. ; Saeed, Sohail ; Ahmad, Khuram Shahzad ; Wong, Wing-Tak</creatorcontrib><description>In the title molecule, C
18
H
20
F
2
N
2
O
2
S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) Å, respectively; the dihedral angle between these two planes is 71.03 (6)°. An intramolecular N—H...O hydrogen bond occurs. In the crystal, N—H...O and O—H...S hydrogen bonds connect the molecules into chains running diagonally across the
bc
plane. C—H...S and C—H...F contacts are also observed.</description><identifier>ISSN: 1600-5368</identifier><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536812018806</identifier><language>eng</language><publisher>International Union of Crystallography</publisher><ispartof>Acta crystallographica. Section E, Structure reports online, 2012-06, Vol.68 (6), p.o1597-o1597</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c354t-e4e76e2d01d543dc6493d463ce078f9f2a11bd336839a3e517c355d62d123e653</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Mohamed, Shaaban K.</creatorcontrib><creatorcontrib>Jaber, Abdel-Aal M.</creatorcontrib><creatorcontrib>Saeed, Sohail</creatorcontrib><creatorcontrib>Ahmad, Khuram Shahzad</creatorcontrib><creatorcontrib>Wong, Wing-Tak</creatorcontrib><title>1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea</title><title>Acta crystallographica. Section E, Structure reports online</title><description>In the title molecule, C
18
H
20
F
2
N
2
O
2
S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) Å, respectively; the dihedral angle between these two planes is 71.03 (6)°. An intramolecular N—H...O hydrogen bond occurs. In the crystal, N—H...O and O—H...S hydrogen bonds connect the molecules into chains running diagonally across the
bc
plane. C—H...S and C—H...F contacts are also observed.</description><issn>1600-5368</issn><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNplkNtKAzEQhoMoWKsP4BtUMJrJZCfby1I8FApeqNchm4Pdsm1Kdgvu29u1IoJXM3z88zH8jF2DuAMQ-v4VSIgCqQQpoCwFnbDRgPjATv_s5-yibddCAGkJIzYHPpl5u7Hbzm458L5xNldp2zc3HPlE3hL3dWz2KSeu-Kr3OX32u1UYAt2qTvsc7CU7i7Zpw9XPHLP3x4e3-TNfvjwt5rMld1iojgcVNAXpBfhCoXekpugVoQtCl3EapQWoPB5-xKnFUIA-3BWepAeJgQocs8XR65Ndm12uNzb3JtnafIOUP4zNXe2aYCpygEReV1VUqEOFztqoSWpBgcrBBUeXy6ltc4i_PhBmaNT8axS_AIf9ZjU</recordid><startdate>20120601</startdate><enddate>20120601</enddate><creator>Mohamed, Shaaban K.</creator><creator>Jaber, Abdel-Aal M.</creator><creator>Saeed, Sohail</creator><creator>Ahmad, Khuram Shahzad</creator><creator>Wong, Wing-Tak</creator><general>International Union of Crystallography</general><scope>AAYXX</scope><scope>CITATION</scope><scope>DOA</scope></search><sort><creationdate>20120601</creationdate><title>1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea</title><author>Mohamed, Shaaban K. ; Jaber, Abdel-Aal M. ; Saeed, Sohail ; Ahmad, Khuram Shahzad ; Wong, Wing-Tak</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c354t-e4e76e2d01d543dc6493d463ce078f9f2a11bd336839a3e517c355d62d123e653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohamed, Shaaban K.</creatorcontrib><creatorcontrib>Jaber, Abdel-Aal M.</creatorcontrib><creatorcontrib>Saeed, Sohail</creatorcontrib><creatorcontrib>Ahmad, Khuram Shahzad</creatorcontrib><creatorcontrib>Wong, Wing-Tak</creatorcontrib><collection>CrossRef</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohamed, Shaaban K.</au><au>Jaber, Abdel-Aal M.</au><au>Saeed, Sohail</au><au>Ahmad, Khuram Shahzad</au><au>Wong, Wing-Tak</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><date>2012-06-01</date><risdate>2012</risdate><volume>68</volume><issue>6</issue><spage>o1597</spage><epage>o1597</epage><pages>o1597-o1597</pages><issn>1600-5368</issn><eissn>1600-5368</eissn><abstract>In the title molecule, C
18
H
20
F
2
N
2
O
2
S, the 2,6-difluoro-4-hydroxyphenyl ring and the carbonylthiourea group are each essentially planar, with maximum deviations of atoms from their mean planes of 0.0113 (14) and 0.1017 (15) Å, respectively; the dihedral angle between these two planes is 71.03 (6)°. An intramolecular N—H...O hydrogen bond occurs. In the crystal, N—H...O and O—H...S hydrogen bonds connect the molecules into chains running diagonally across the
bc
plane. C—H...S and C—H...F contacts are also observed.</abstract><pub>International Union of Crystallography</pub><doi>10.1107/S1600536812018806</doi><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1600-5368 |
| ispartof | Acta crystallographica. Section E, Structure reports online, 2012-06, Vol.68 (6), p.o1597-o1597 |
| issn | 1600-5368 1600-5368 |
| language | eng |
| recordid | cdi_doaj_primary_oai_doaj_org_article_b6c1366d7bbf437eb3caaf762706e685 |
| source | Open Access: PubMed Central |
| title | 1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T06%3A43%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-doaj_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=1-(Adamantan-1-ylcarbonyl)-3-(2,6-difluoro-4-hydroxyphenyl)thiourea&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Structure%20reports%20online&rft.au=Mohamed,%20Shaaban%20K.&rft.date=2012-06-01&rft.volume=68&rft.issue=6&rft.spage=o1597&rft.epage=o1597&rft.pages=o1597-o1597&rft.issn=1600-5368&rft.eissn=1600-5368&rft_id=info:doi/10.1107/S1600536812018806&rft_dat=%3Cdoaj_cross%3Eoai_doaj_org_article_b6c1366d7bbf437eb3caaf762706e685%3C/doaj_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c354t-e4e76e2d01d543dc6493d463ce078f9f2a11bd336839a3e517c355d62d123e653%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |