Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate

The title compound, C 6 H 15 N 2 O + ·C 6 H 2 N 3 O 7 − ·H 2 O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C 6 H 15 N 2 O) + , one anion (C 6 H 2 N 3 O 7 ) − and a water molecule in the asymmetric...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2023-01, Vol.79 (1), p.8-13
Main Authors: Chidambaranathan, Balasubramanian, Sivaraj, Settu, Selvakumar, Shanmugam
Format: Article
Language:English
Subjects:
hirshfeld surface
hydrogen bond
morpholine
nmr
single-crystal x-ray study
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Summary:The title compound, C 6 H 15 N 2 O + ·C 6 H 2 N 3 O 7 − ·H 2 O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C 6 H 15 N 2 O) + , one anion (C 6 H 2 N 3 O 7 ) − and a water molecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C—H...O, O—H...O, O—H...N and N—H...O hydrogen-bonding interactions and π–π stacking. The intermolecular interactions of the synthesized compound were quantified by Hirshfeld surface analysis.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989022011409