Enhancing Insight into Photochemical Weathering of Flax and Miscanthus: Exploring Diverse Chemical Compositions and Composite Materials

• Published in: Molecules (Basel, Switzerland) Switzerland), 2024-08, Vol.29 (16), p.3945
• Main Authors: El Hage, Roland, Carvalho Martins, Raíssa, Brendlé, Clément, Lafon-Pham, Dominique, Sonnier, Rodolphe
• Format: Article
• Language: English
• Subjects: accelerated weathering; Aging; Cellulose; chemical composition; Chemical Sciences; color monitoring; Composite materials; Environmental Sciences; Fatty acids; Infrared spectroscopy; Lignin; Lignocellulose; lignocellulosic biomass; Oxidation; Photodegradation; Polyphenols; PP composites; Scanning electron microscopy; Sterols; thermal stability; Ultraviolet radiation
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules29163945

The accelerated weathering of flax and miscanthus fibers possessing distinct chemical compositions was investigated. The chosen fibers included raw, extractive-free (EF) and delignified samples (x3), alone and used as fillers in a stabilized polypropylene blue matrix (PP). Modifications in both color and the chemical composition of the fibers throughout the weathering process under ultraviolet (UV) light were meticulously tracked and analyzed by spectrophotometry and attenuated total reflectance with Fourier-transform infrared spectroscopy (ATR-FTIR). The inherent nature and composition of the selected fibers led to varied color-change tendencies. Raw and EF flax fibers exhibited lightening effects, while raw and EF miscanthus fibers demonstrated darkening effects. Extractives exhibited negligible influence on the color alteration of both flax and miscanthus fibers. This disparity between the fibers correlates with their respective lignin content and type, and the significant formation of carbonyl (C=O) groups in miscanthus. Better stability was noted for delignified flax fibers. A comparative study was achieved by weathering the PP matrix containing these various fibers. Contrary to the weathering observations on individual fibers, it was noted that composites containing raw and EF flax fibers exhibited significant color degradation. The other fiber-containing formulations showed enhanced color stability when compared to the pure PP matrix. The study highlights that the UV stability of composites depends on their thermal history. As confirmed by thermogravimetric analysis (TGA), fiber degradation during extrusion may affect UV stability, a factor that is not apparent when fibers alone are subjected to UV aging.